Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
By the above process, one part of phosphorus may be detected in 100,000
parts of substance. Another method for the detection of this poison in
very minute quantities is that proposed by Dussart (_Compt. Rend._,
xliii. 1126), and modified by Blondlot (_Compt. Rend._, lii. 1197).
The test is based on the fact that when phosphorus is exposed to the
action of _nascent hydrogen_ in a Marsh‘s apparatus, it burns with an
emerald-green flame. In order to avoid the yellow colouring of the
flame produced by the sodium in glass, Blondlot recommends the use of
a platinum jet. As the green colour is more or less interfered with by
the presence of organic matters, he passes the gas through a solution
of nitrate of silver; the resulting precipitate is then placed in
another hydrogen apparatus, as just mentioned, and the colour of the
flame of the issuing gas noted. Phosphorus may become decomposed in
the body; and as phosphoric acid is taken in most articles of food,
the only satisfactory evidence of phosphorus having been taken is to
produce it in its free state, or at least to exhibit its luminosity.
The detection of the colouring matter of lucifer matches in the stomach
or vomited matters will point to the probable nature of the poison, and
whence it was derived.
_Scherer‘s Test_ is based on the reducing action of phosphorus on
nitrate of silver, which it blackens. The suspected material should be
placed in a flask or in a Dowzard‘s apparatus for Gutzeit‘s test for
arsenic, lead acetate is added to the material to fix the H₂S, and some
lead acetate solution placed in each cell. A little ether is added to
the mixture, and the flask or top of the apparatus capped with paper
moistened with nitrate of silver, and set aside for some hours in a
dark place. If phosphorus be present the paper will be blackened from
deposition of metallic silver.
_Fatal Period._--From half an hour to twenty days or more.
_Fatal Dose._--One grain and a half. The smallest fatal dose recorded
for an adult is one-eighth of a grain. An infant five weeks old died
from sucking a single match head, which probably contained one-fiftieth
of a grain of phosphorus. Recovery has taken place after four and six
grains have been taken.
_Treatment._--The stomach pump or syphon tube should be used as soon as
possible, and the stomach well washed out with warm water containing
a drachm of old oil of turpentine to the pint. If the turpentine be
not readily obtained, “sanitas” should be used with the water, or a
1 per cent. solution of permanganate of potash. After washing the
stomach, the old oil of turpentine, or the French oil of turpentine, or
“sanitas” may be administered in half to one drachm doses in mucilage
and water every fifteen minutes for several doses, and afterwards three
or four times daily. The 1 per cent. solution of potassium permanganate
may be administered in copious drinks.
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