When an electron comes out of the nucleus of an atom, it increases
[Pg 117]
the net charge in the nucleus by one, and therefore increases the
atomic number by one. Thus it is possible for the atomic number to be
increased by the loss of something from the nucleus, provided what is
lost is an electron. But although the atomic number is increased, the
atomic weight is not. The electron weighs so little that its loss makes
no appreciable difference to the atomic weight; moreover, since the net
charge on the nucleus is increased by one, the atom will secure another
planetary electron as soon as possible. Thus in the end the effect of
a radio-active change by the emission of -particles ought to
be to leave the atomic weight unchanged while increasing the atomic
number by one. The result of one emission of -particles
followed by two of -particles is thus to deprive the nucleus
of a helium nucleus and two electrons, without, in the end, changing
the atomic number. Thus uranium has two very stable forms, called
uranium I and uranium II. Uranium I is the great-grandfather of uranium
II. Uranium I, by means of -rays, gives rise to uranium
, of which half decays in little less than 24 days. Uranium
gives rise to uranium by means of -rays; half
of Uranium decays in just over a minute. Uranium , by
means of -rays again, gives rise to uranium II. Uranium I and
[Pg 118]
II both have atomic number 92; uranium has atomic number 90,
and uranium has atomic number 91. Thus the two stable forms
of uranium have the same atomic number although they have different
atomic weights (238 and 234). Again, the various radio-active series
all end in some form of lead; the three forms are called respectively
radium-lead, actinium-lead, and thorium-lead, after their respective
ancestors. These all have the same atomic number as ordinary lead
(82), but their atomic weights differ. Ordinary lead has the atomic
weight 207.2; radium-lead, 206.0; thorium-lead, 207.9. It is probable,
however, that ordinary lead is a mixture of two or more kinds of lead,
and perhaps this is also the case with what counts as thorium-lead. The
reason for this view is that it is now probable that every perfectly
pure element has an atomic weight which is almost exactly an integer.
Public-domain text, read in full here on John Shaqi.
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