When two elements have the same atomic number, they are called
“isotopes.” Apart from radio-activity, the only discoverable property
in which isotopes differ is atomic weight. They have the same net
charge in the nucleus, and therefore the same number of planetary
electrons, and the same possible orbits of the electrons. Consequently
their chemical properties are the same, their optical spectra are
[Pg 119]
the same, and even their X-ray spectra are the same. All this is as
it should be according to theory. It is no wonder that the existence
of isotopes remained so long unknown. They first became known through
observations of radio-active products. But it has lately become
known, through the work of F. W. Aston, that there are many isotopes
in regions of the periodic table where radio-activity can hardly be
supposed to take place. Aston found means, in a gas containing atoms of
different weights, by which he separated the heavier and lighter atoms;
he thus obtained two pure gases out of a mixture which had hitherto
been wrongly supposed to be pure. The result was to show that atomic
weights are very approximately integers in many cases in which this
was thought not to be the case. Thus neon, which has the atomic weight
20.2, is found to consist of a mixture of two gases, one having atomic
weight 20, the other 22. Chlorine, which has the atomic weight 35.46,
is a mixture of two kinds having atomic weights 35 and 37 respectively.
Krypton turns out to consist of as many as six isotopes; xenon, of
seven, two of which however are more or less doubtful.
Public-domain text, read in full here on John Shaqi.
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