The volcanic agglomerates and breccias, in the south-west of Ayrshire, attain a great development in several centres probably at or near the original volcanic vents. They present several distinct petrographical types. The remarkable neck-like hill of Knockdolian in the Stinchar Valley is made of a coarse breccia composed mainly of angular pieces of dull greyish-green fine-grained diabase. The breccias and agglomerates of Bennane Head in some parts consist largely of broken-up shales, flinty mudstone, black radiolarian flint or chert, and abundant fragments of andesites and felsites. In other parts the volcanic material predominates, including angular and subangular fragments of various somewhat basic lavas, lumps of vesicular slag and pieces of pumice. Here and there much calcite is diffused through the matrix in strings, veins and patches, which enclose the lapilli. The agglomerate north of Lendalfoot possesses a greenish, somewhat serpentinous matrix, through which immense numbers of tabular felspar crystals are scattered. Similar crystals also occur abundantly in embedded blocks of one of the purplish diabase-porphyrites, which occurs in mass on the shore and inland, and closely resembles the rock of Carnethy in the Old Red Sandstone volcanic series of the Pentland Hills. Yet another and very distinct type of agglomerate is to be seen on the Mains Hill south-east of Ballantrae. It is a coarse rock, enclosing blocks up to a yard or more in diameter, of a fine compact purplish porphyrite, with large crystals of plagioclase and smaller ones of augite. In some places immense numbers of the small lapilli in the matrix consist of an extremely fine vesicular pumice. Small perfect and larger broken crystals of augite are likewise abundant in some of the greenish, more basic parts of the mass. These greenish serpentinous parts and the numerous augite crystals point to the explosion of some tolerably basic pyroxenic lava. A similar dark green, almost black, rock, with augite crystals, which sometimes measure a quarter of an inch in diameter, occurs near Sanquhar in Nithsdale. It presents a close resemblance to the agglomerate of Rhobell Fawr, already alluded to. So far as these Scottish agglomerates have yet been microscopically examined, they have been found to be composed of crystals, crystal-fragments, and lapilli derived partly from lavas similar to those above described, and partly from felsitic and other rocks which have not yet been observed here in the form of lavas.