The army behind the armyPowell, E. Alexander (Edward Alexander)
History
The army behind the army
Powell, E. Alexander (Edward Alexander)
United States. Army; World War, 1914-1918 -- United States
Chlorine, which is the first gas the Germans used and which is an
important constituent of nearly all the other toxic-gases, is derived
from ordinary table-salt. It is prepared by passing a current of
electricity through a solution of salt, by which process chlorine is
liberated and caustic soda formed. At ordinary temperatures chlorine is a
greenish-yellow gas of strong, suffocating odor, but by means of cold and
pressure it can be readily condensed to a liquid and is usually shipped
in that form, stored in strong cylinders. The apparatus in which the salt
is decomposed by the electric current is known as a cell. The salt, upon
arrival at the arsenal, was taken to the brine building and dumped into
large concrete tanks kept partially filled with water, the resulting
brine being drawn off, purified, and pumped to the cell-house as needed.
The interior of this building was filled with cells, nearly 4,000 in all,
through which was passed a direct current of approximately 260 volts.
The chlorine thus extracted from the brine was liquefied by compressing
it through the agency of a falling column of sulphuric acid and then
cooling the compressed gas by refrigeration. Though chlorine has long
been manufactured in the United States for chemical purposes, a constant
supply of it was so essential for the preparation of the other gases that
Colonel Walker insisted that it should be produced at Edgewood, thus
making the government independent of private manufacturers.
Chlorpicrin, while not so poisonous as some of the other gases, is,
nevertheless, an active poison and has, in addition, pronounced lachrymal
(tear-producing) and nauseating qualities. Though chlorpicrin is fatal
when taken in large quantities, it is almost impossible to inhale much
of it because of its terribly nauseating effect. The inhalation of four
cubic inches of it causes violent vomiting. Chlorpicrin is produced by
the action of picric acid upon chlorine in the form of bleaching-powder.
The bleaching-powder, after being diluted with water to the consistency
of thick cream, is mixed with a solution of calcium picrate in large
stills holding 5,000 or more gallons. A jet of live steam is introduced
at the bottom of the still and the reaction begins at once, the resulting
chlorpicrin passing out of the still into condensers. This mixture of
chlorpicrin and water is then run into tanks. As chlorpicrin does not
dissolve in water, it gradually settles to the bottom and is drawn off
and loaded directly into the shell.
Public-domain text, read in full here on John Shaqi.
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