The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.Piesse, G. W. Septimus (George William Septimus)
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The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.
Piesse, G. W. Septimus (George William Septimus)
Cosmetics; Perfumes
(_Read before the Chemical Discussion Society._)
I have recently made some experiments with oil of lemons, of which the
following is a short account:--
Being constantly annoyed by the deposit and alteration in my essence of
lemons, I have tried various methods of remedying the inconvenience.
I first tried redistilling it, but besides the loss consequent on
distilling small quantities, the flavor is thereby impaired. As the oil
became brighter when heated, I anticipated that all its precipitable
matter would be thrown down at a low temperature, and I applied a
freezing mixture, keeping the oil at zero for some hours. No such
change, however, took place.
The plan which I ultimately decided upon as the best which I had
arrived at, was to shake up the oil with a little boiling water, and to
leave the water in the bottle; a mucilaginous preparation forms on the
top of the water, and acquires a certain tenacity, so that the oil may
be poured off to nearly the last, without disturbing the deposit.
Perhaps cold water would answer equally well, were it carefully agitated
with the oil and allowed some time to settle. A consideration of its
origin and constitution, indeed, strengthens this opinion; for although
lemon otto is obtained both by distillation and expression, that which
is usually found in commerce is prepared by removing the "flavedo" of
lemons with a rasp, and afterwards expressing it in a hair sack,
allowing the filtrate to stand, that it may deposit some of its
impurities, decanting and filtering. Thus obtained it still contains a
certain amount of mucilaginous matter, which undergoes spontaneous
decomposition, and thus (acting, in short, as a ferment) accelerates a
similar change in the oil itself. If this view of its decomposition be a
correct one, we evidently, in removing this matter by means of the
water, get rid of a great source of alteration, and attain the same
result as we should by distillation, without its waste or deterioration
in flavor.
I am, however, aware that some consider the deposit to be modified
resin.[H] Some curious experiments of Saussure have shown that volatile
oils absorb oxygen immediately they have been drawn from the plant, and
are partially converted into a resin, which remains dissolved in the
remainder of the essence.
He remarked that this property of absorbing oxygen gradually increases,
until a maximum is attained, and again diminishes after a certain lapse
of time. In the oil of lavender this maximum remained only seven days,
during each of which it absorbed seven times its volume of oxygen. In
the oil of lemons the maximum was not attained until at the end of a
month; it then lasted twenty-six days; during each of which it absorbed
twice its volume of oxygen. The oil of turpentine did not attain the
maximum for five months, it then remained for one month, during which
time it absorbed daily its own volume of oxygen.
Public-domain text, read in full here on John Shaqi.
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