The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.Piesse, G. W. Septimus (George William Septimus)
History
The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.
Piesse, G. W. Septimus (George William Septimus)
Cosmetics; Perfumes
To obtain it we treat the flowers with boiling absolute alcohol, which
dissolves the coloring matter in the heat, and by cooling almost
completely allows it again to precipitate. The yellow deposit which is
obtained in this way, is not pure xanthine, as it contains a rather
considerable quantity of oil. To separate this oil we have recourse to a
moderate saponification; thus, we heat the yellow precipitate with a
small quantity of alkali to saponify the fatty body mixed with the
xanthine, which even contains the xanthine dissolved. As the coloring
matter is soluble in the soap solution, we do not treat the mass with
water, but decompose it with an acid which isolates the xanthine and the
fatty acids resulting from the saponification. This precipitate we treat
with cold alcohol, which leaves behind the fatty acids, and dissolves
the xanthine. This substance is a fine yellow color, insoluble in water,
but soluble in alcohol and ether, which are thereby colored golden
yellow. It appears to be uncrystallizable, and possesses the general
properties of resins.
Xanthine, in combination with cyanine, modified by the various juices of
plants, communicates in variable proportions orange-yellow, scarlet-red,
and red colors to flowers.
_Xantheine, or the Coloring Matter soluble in water._--By the
preparation of the substance which colors yellow certain dahlias, it is
at once perceived that it has no analogy to xanthine. The latter is as
known insoluble in water, while the coloring matter under consideration
is readily soluble in water.
To obtain the xanthine we treat the petals of yellow flowering dahlias
with alcohol, which quickly dissolves the yellow coloring matter,
besides the fat and resin. The solution is evaporated to dryness, and
the residue treated with water, whereby the fat and resin are separated.
The water is again evaporated to dryness, and the residue treated with
absolute alcohol. The resulting solution diluted with water is mixed
with neutral acetate of lead, which precipitates the coloring matters.
The lead precipitate is then decomposed with sulphuric acid, upon which
the xantheine which remains dissolved in the water is purified by
alcohol.
Xantheine is soluble in water, alcohol, and ether, but crystallizes from
none of these solutions. Alkalies color it intensely brown. Its power of
coloration is considerable. It dyes various fabrics of a yellow tone,
which is without brilliancy. Acids again destroy the brown coloration
produced by alkalies. Xantheine combines with most metallic bases, and
forms therewith yellow or brown insoluble lakes.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account