The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.Piesse, G. W. Septimus (George William Septimus)
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The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.
Piesse, G. W. Septimus (George William Septimus)
Cosmetics; Perfumes
The whole of the crude acid is to be rectified with the addition of an
ounce of sulphuric acid to every pound. The distillate is then saturated
with fused chloride of calcium, and redistilled. The product will be
about 28 ounces of pure butyric acid. To prepare the butyric acid or
essence of pine-apple, from this acid proceed as follows:--Mix, by
weight, three parts of butyric acid with six parts of alcohol, and two
parts of sulphuric acid in a retort, and submit the whole, with a
sufficient heat, to a gentle distillation, until the fluid which passes
over ceases to emit a fruity odor. By treating the distillate with
chloride of calcium, and by its redistillation, the pure ether may be
obtained.
The boiling-point of butyric ether is 238 deg. Fahr. Its specific gravity,
0.904, and its formula,
C_{12}H_{12}O_{4}, or C_{4}H_{5}O + C_{8}H_{7}O_{3}.
Bensch's process, above described, for the production of butyric acid,
affords a remarkable exemplification of the extraordinary
transformations that organic bodies undergo in contact with ferment, or
by catalytic action. When cane sugar is treated with tartaric acid,
especially under the influence of heat, it is converted into grape
sugar. This grape sugar, in the presence of decomposing nitrogenous
substances, such as cheese, is transformed in the first instance into
lactic acid, which combines with the lime of the chalk. The acid of the
lactate of lime, thus produced, is by the further influence of the
ferment changed into butyric acid. Hence, butyrate of lime is the final
result of the catalytic action in the process we have here recommended.
* * * * *
PREPARATION OF CRUDE PELARGONATE OF ETHYL-OXIDE (ESSENCE OF QUINCE.)
BY DR. R. WAGNER.
Public-domain text, read in full here on John Shaqi.
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