The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
While the band spectra with a spectroscope of high resolving power
can be more or less completely resolved into lines, this is not the
case with the _continuous spectra_. They are emitted not only by
glowing solids (cf. p. 54), but also by many gaseous substances. When
such gases are exposed to electric discharges they emit, in addition to
the line spectra and band spectra, continuous spectra which in certain
parts of the spectrum furnish a background for bright lines which come
out more strongly. It might seem impossible to correlate these with the
Bohr theory; but in reality a spectrum does not always have to consist
of sharp lines. This can at once be seen from the correspondence
principle. If the motions in the stationary states are of such
nature that they can be resolved into a number of discrete harmonic
oscillations each with its own period (for instance the orbit of an
electron in a rotating ellipse; cf. p. 149), then, according to the
correspondence principle, in the transition between two such stationary
states there are produced sharp spectral lines “corresponding” to these
harmonic components. But not all motions of atomic systems can be thus
resolved into a number of definite harmonic oscillations. When this
cannot be done, the stationary states cannot be expected to be such
that transitions between them produce radiation which can be resolved
into sharp lines.
A simple example, where it is easily intelligible that the Bohr theory
will not lead to sharp lines, is obtained in a simple consideration
of the hydrogen atom. Let us examine the lines belonging to the
Balmer series which are produced when an electron passes to the No. 2
orbit from an orbit with higher orbit number, which is farther from
the nucleus. As has been said, we obtain here an upper limit for the
frequency corresponding to a value of the outer orbit number which is
infinite; this means, in reality, that the electron in one jump comes
in from a distance so great that the attraction of the nucleus is
infinitely small. The energy released by such a jump is the same as the
ionizing energy A₂ which is required to eject the electron from the
orbit No. 2 and drive it from the atom. It is here assumed, however,
that the electron out in the distance was practically at rest. If the
captured electron has a certain initial velocity outside, it will have
a corresponding kinetic energy A. When in one jump this electron comes
from the outside into orbit No. 2, the energy lost by the electron
and emitted in the form of radiation will be the sum of the ionizing
energy A₂ and the original kinetic energy A. The frequency ν will then
become greater than that corresponding to A₂; and since the velocity
of the electron before it is captured is not restricted to certain
definite values, neither is the value of ν. The radiation from a great
quantity of hydrogen atoms which are binding electrons in this way
will, in the spectrum, not be concentrated in certain lines, but will
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