The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
In 1913 the German physicist Franck began a series of experiments by
methods which made it possible to regulate accurately the velocity
of the electrons, and to determine the kinetic energy before and
after collisions with atoms. He first applied the methods to mercury
vapour, where the conditions are particularly simple, since the mercury
molecules consist of only one atom. Franck bombarded mercury vapour
with electrons all of which had the same velocity. He then showed that
if the kinetic energy of the electrons was less than 4·9 volts the
collisions with the atoms were completely “elastic,” _i.e._, the
direction of the electron could be changed by the collision, but not
its velocity. If, however, the velocity of the impinging electrons was
increased so much that it was somewhat larger than 4·9 volts, there
was an abrupt change in the situation, since many of the collisions
became completely inelastic, _i.e._, the colliding electron lost
its entire velocity and gave up its entire kinetic energy to the atom.
If the initial velocity was even greater, so that the kinetic energy
of the colliding electron was 6 volts, for instance, then when the
collision took place there would always be lost a kinetic energy of 4·9
volts, since the electrons would either preserve their kinetic energy
intact or have it reduced to 1·1 volt (cf. Fig. 30).
[Illustration: FIG. 30.—Schematic drawing of Franck’s
experiment with electron collisions. _G_ is a glowing metal wire
which emits electrons. If between _G_ and the wire net _T_
there is a difference of potential of 6 volts, the electrons will pass
through the holes of the net with great velocity out into the space
_R_, where there is mercury vapour. _a_ represents a free
electron _F_ and a mercury atom _Hg_ before the collision,
while _b_ represents them after the collision; with the collision
_F_ loses a kinetic energy corresponding to 4·9 volts; at the
same time a bound electron _B_ in the atom goes over to a larger
stationary orbit.]
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