The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
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The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The method Bohr used in his attempt to solve the problem was to study
_how a neutral normal atom may gradually be formed by the successive
capturing and binding of the individual electrons in the field of
force about the nucleus of the atom_. He began by assuming that he
had a solitary nucleus with a positive charge of a given magnitude.
To this nucleus free electrons are now added, one after the other,
until the nucleus has taken on the number sufficient to neutralize the
nuclear charge. Each individual electron undergoes a “binding” process,
_i.e._ it can move in different possible stationary orbits about
the nucleus and the electrons already bound. With the emission of
radiation it can go from stationary states with greater energy to
others with less energy, ending its journey by remaining in the orbit
which corresponds to the least possible energy. We may designate
this state of least energy as the normal state of the system, which,
however, is only a positive atomic ion, so long as all the electrons
needed for neutralization are not yet captured.
From the exposition in the preceding chapter it will be seen that
the ordinary series spectra (arc spectra) may be considered as
corresponding to the last stage in this formation process, since the
emission of each line in such a spectrum is due to a transition between
two stationary states in each of which N-1 electrons are bound in their
normal state, _i.e._ as tight as possible, by the nucleus, while
the Nth electron moves in an orbit mainly outside the region of the
other electrons. In the same way the spark spectra give witness of the
last stage but one of the formation process of the atom, since here
N-2 electrons are bound in their normal state while an N-1th electron
moves in an orbit large compared with the dimensions of the orbits
of the inner electrons. From these remarks it will be clear that the
study of the series spectra is of great importance for the closer
investigation of the process of formation of the atom outlined above.
Furthermore, the general ideas of the correspondence principle, which
directly connects the possibility of transition from one stationary
state to another with the motion of the electron, has been very useful
in throwing light on the individual capturing processes and on the
stability of the electronic configurations formed by these. In what
follows we cannot, however, reproduce Bohr’s arguments at length; we
must satisfy ourselves with some hints here and there, and for the rest
restrict ourselves to giving some of the principal results.
Public-domain text, read in full here on John Shaqi.
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