The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The one electron of hydrogen will, upon being captured, first be at
“rest” when it reaches the 1₁-path, and we might perhaps be led to
expect that in the atoms with greater nuclear charges the electrons in
the normal state also would be in the one quantum orbit 1₁, because
to this corresponds the least energy in hydrogen. This assumption
formed actually the basis of Bohr’s work of 1913 on the structure of
the heavier atoms. It cannot be maintained, however. Considerations
of theoretical and empirical nature lead to the assumption that
the electrons which already are gathered about the nucleus can make
room only to a certain extent for new ones, moving in orbits of the
same principal quantum number. Those electrons which are captured
later are kept at an appropriate distance; they are, for instance,
prevented from passing from a 3-quantum orbit to a 2-quantum one,
if the number of electrons moving in 2-quantum orbits has reached a
certain maximum value. When it is said that the captured electrons
end in the stationary state which corresponds to the least energy,
it must, therefore, mean, not the 1-quantum orbit, but the innermost
possible under the existing circumstances. _The final result will be
that the electrons are distributed in groups, which are characterized
each by their quantum numbers in such a way that passing from the
nucleus to the surface of the atom, the successive groups correspond to
successive integer values of the quantum number, the innermost group
being characterized by the quantum number one. Moreover, each group is
subdivided into sub-groups corresponding to the different values which
the auxiliary quantum number may take._
That the electrons first collected keep the latecomers at an
appropriate distance must be understood with reservations; a new
electron moving in an elongated orbit can very well come into the
territory already occupied; in fact, it may come closer to the nucleus
than some of the innermost groups of electrons. In case an outer
electron thus dives into the inner groups, it makes a very short visit,
travelling about the nucleus like a comet which at one time on its
elongated orbit comes in among the planets and perhaps draws closer to
the sun than the innermost planet, but during the greater part of its
travelling time moves in distant regions beyond the boundaries of the
planetary system. It is a very important characteristic of the Bohr
theory of atomic architecture that the outer electrons thus penetrate
far into the interior of the atom and thus chain the whole system
together.
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