The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
-------+------+------------------------------------------------------+
| | Quantum Numbers. |
|Atomic+---+---+---+---+---+---+---+---+---+---+---+---+---+--+
|Number| 5₁| 5₂| 5₃| 5₄ | 5₅| 6₁| 6₂| 6₃| 6₄| 6₅| 6₆| 7₁ | 7₂| 7₃|
-------+------+---+---+---+---+---+---+---+---+---+---+---+---+---+--+
Helium | 2 | | | | | | | | | | | | | | |
Neon | 10 | | | | | | | | | | | | | | |
Argon | 18 | | | | | | | | | | | | | | |
Krypton| 36 | | | | | | | | | | | | | | |
Xenon | 54 | 4 | 4 | - | - | - | | | | | | | | | |
Niton | 86 | 6 | 6 | 6 | - | - | 4 | 4 | - | - | - | - | | | |
? | 118 | 8 | 8 | 8 | 8 | - | 6 | 6 | 6 | - | - | - | 4 | 4 | -|
-------+------+---+---+---+---+---+---+---+---+---+---+---+---+---+--+
The elements _fluorine_, _oxygen_ and _nitrogen_ can
attain the ideal neon-architecture by binding respectively one, two
and three additional electrons. Naturally they do not become neon
atoms, but merely negative atomic ions with single, double or triple
charge; and their tendency in this direction appears in their character
of monovalent, divalent and trivalent electronegative elements
respectively. If we return to carbon it can probably not become a
tetravalent negative ion by binding four free electrons; but in the
typical carbon compound, methane (CH₄), the neon ideal is realized
in another manner. In fact, it is reasonable to assume that the four
electrons of the hydrogen atoms together with the six of the carbon
atom give approximately a neon-architecture. The four hydrogen nuclei
naturally cannot be combined with the carbon nucleus; the mutual
repulsions keep them at a distance. They will probably assume very
symmetrical positions within the electron system which holds them
together. The nitrogen atom may in a similar way find completion in
a neutral molecule with neon-architecture, if it unites with three
hydrogen atoms to form ammonia NH₃; but the three hydrogen nuclei,
although having symmetrical positions, will not lie in the same plane
as the nitrogen nucleus. The electric centre of gravity for the
positive nuclei will therefore not coincide with the centre of gravity
for the negative electron system. The molecule obtains thus what might
be called a positive and a negative pole, and this dipolar character
appears in the electrical action of ammonia (its dielectric constant).
Something similar holds true for the water molecule, where, in a
neon-architecture of electrons, in addition to the oxygen nucleus in
the centre there are two hydrogen nuclei which are not co-linear with
the oxygen nucleus.
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