The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
When the reorganization is almost completed, we come to
the blotting out of chemical differences, particularly known from the
triad, _iron_, _cobalt_ and _nickel_. Moreover, there
comes a fluctuation in the valency of the elements. Iron can, as has
been said, be divalent, trivalent or hexavalent. This oscillation in
valency begins in _titanium_.
We should perhaps expect that the reconstruction would be completed
long before nickel (28) is reached, because even with twenty-two
electrons we could get four orbits of each of the 3-quantum types
(3₁, 3₂ and 3₃); but from the chemical facts we are led to assume
that in a completed group of 3-quantum orbits there can be room for
six electrons in each sub-group. At first sight we should, then,
expect the end of the reconstruction with nickel, which has indeed
eighteen electrons more than neon where the group of 2-quantum orbits
was completed. We might expect that nickel would be an inert element
in the series with helium, neon, and argon. On the contrary, nickel
merely imitates cobalt. This is explained by the fact that the group of
eighteen 3-quantum orbits, although it has a symmetric architecture,
is weakly constructed if the nuclear charge is not sufficiently large.
The binding of this group is too weak for it to exist as the outer
group in a neutral atom. In _nickel_ the electrons, in a less
symmetrical manner, will probably arrange themselves with seventeen
3-quantum orbits and one 4-quantum orbit.
The group of eighteen 3-quantum orbits becomes stable, however, when
the nuclear charge is equal to or larger than 29, in which case it
can become the outer group in a positive ion. In this we find the
explanation of the properties of the atom of _copper_. The
neutral copper atom has its twenty-ninth electron bound in a 4₁ orbit
consisting of oblong loops (cf. diagram at the end); this electron
can easily be freed and leaves a positive monovalent copper ion with
a symmetrical architecture. Even under these circumstances, although
possessing a certain stability, the ion is not very firmly constructed.
Thus the fact that copper can be both monovalent and divalent, must be
explained by the assumption that for a nuclear charge 29, the 3-quantum
group still easily loses an electron.
When we come to _zinc_ (30) the group of eighteen is more firmly
bound; zinc is a pronounced divalent metal which in its properties
reminds us of calcium and magnesium. From zinc (30) to krypton (36) we
have a series of elements which in a certain way repeat the series from
magnesium (12) to argon (18).
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