The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The elements in which the 4-quantum group is in a state of
reconstruction are, in Fig. 34, enclosed in the inner frame in the
sixth period. Moreover, in the outer frame all elements are enclosed
where the group of 5-quantum orbits is in a state of reconstruction,
which started, even before cerium in lanthanum (57), where the
fifty-fifth electron in the normal state is bound in a 5₃ orbit. The
element _cassiopeium_, with atomic number 71, which is the last
of the rare earths, stands just outside the inner frame, because
in the normal neutral atom of this element the 4-quantum group is
just completed; this group, instead of eighteen electrons with six
electrons in each sub-group, consists now of thirty-two electrons with
eight electrons in each sub-group. The theory was able to predict that
the element with atomic number 72, which until a short time ago had
never been found, and the properties of which had been the subject of
some discussion, must in its chemical properties differ considerably
from the trivalent rare earths and show a resemblance to the
tetravalent elements zirconium (40), and thorium (90). This expectation
has recently been confirmed by the work of Hevesy and Coster in
Copenhagen, who have observed, by means of X-ray investigations,
that most zircon minerals contain considerable quantities (1 to 10
per cent.) of an element of atomic number 72, which has chemical
properties resembling very much those of zirconium, and which on this
account had hitherto not been detected by chemical investigation. A
preliminary investigation of the atomic weight of this new element, for
which its discoverers have proposed the name _hafnium_ (Hafnia =
Copenhagen), gave values lying between 178-180, in accordance with what
might be expected from the atomic weight of the elements (71) and (73).
(Cf. p. 23.)
The further completion of the groups of 5- and 6-quantum orbits, which
in the rare earths had temporarily come to a standstill, is resumed
in hafnium and goes on in a way very similar to that in which the 4-
and 5-quantum groups in the fifth, and the 3- and 4-quantum groups in
the fourth period underwent completion. Thus the reconstruction of
the 5-quantum group which began in lanthanum, and which receives a
characteristic expression in the triad of the platinum metals, has come
to a provisional conclusion in _gold_ (79), gold being the first
element outside the two frames which, in Fig. 34, appear in the sixth
period. The neutral gold atom possesses, in its normal state—besides
two 1-quantum orbits, eight 2-quantum orbits, eighteen 3-quantum
orbits, thirty-two 4-quantum orbits and eighteen 5-quantum orbits—one
loosely bound electron in a 6₁ orbit.
In _niton_ (86), finally, we meet again an inactive gas, the
structure of the atom of which is indicated in the table on p. 196.
Public-domain text, read in full here on John Shaqi.
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