The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The number which formerly indicated simply the position of an
element in the periodic system has thus obtained a profound physical
significance, and in comparison the atomic weight has come to have
but a secondary meaning. The inversion of argon and potassium in the
periodic system (mentioned on p. 21), which seemed to be an exception
to the regularity displayed by the system as a whole, obtains an easy
explanation on the van den Broek rule; for to explain the inversion
we need only assume that potassium has one electron more than argon,
though its atomic weight is less than that of argon. We see at once
that the atomic weight and number of electrons (or what is the same
thing—the nuclear charge) are not directly correlated to each other.
And since the periodic system based on the atomic number represents
the correct arrangement of the elements according to their respective
properties (especially their chemical properties), we are led naturally
to the conclusion that it is the atomic number and not the atomic
weight that determines chemical characteristics.
The conception of the relatively great importance of the atomic number
as compared with the atomic weight has in recent years received
overwhelming support from the researches of Soddy, Fajans, Russell,
Hevesy and others who have discovered the existence of so-called
_isotope elements_ (from the Greek _isos_ = same, and
_topos_ = place), substances with different nuclear masses (atomic
weights) and different radioactive properties (if there are any),
but with the same nuclear charge, the same number of electrons and,
consequently, occupying the same place in the periodic system. Two such
isotopes are practically equivalent in all their chemical properties as
well as in most of their physical characteristics. One of the oldest
examples of isotopes is provided by ordinary lead with the atomic
weight 207·2 and the substance found in pitchblende with the atomic
weight 206, but identical, chemically, with ordinary lead. This latter
form of lead has already been referred to on p. 79 as the end product
of radioactive disintegrations, and hence it is sometimes called radium
lead.
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