The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
This distribution of the radiation over widely differing wave-lengths
can be investigated by examining spectroscopically the light emitted
from the peep-hole in the cavity. Then, by means of a bolometer or some
other instrument, the heat development in the different portions of the
spectrum can be measured. At a temperature of 1500° C., for example,
one will find that the maximum energy is represented for rays of
wave-length in the close vicinity of 1·8 μ, _i.e._ in the extreme
infra-red. If the temperature is raised, the energy maximum travels off
in the direction of the violet end of the spectrum; if the temperature
is lowered, it will move farther down into the infra-red.
It is also possible to make a theoretical calculation of the
distribution of energy in the spectrum of the black-body radiation
at a given temperature. But the results obtained do not agree with
experiment. The English physicists, Rayleigh and Jeans, developed
on the basis of the classical electrodynamic laws and by apparently
convincing arguments a distribution law according to which actual
radiation equilibrium becomes impossible, since if it were true the
energy in the radiation would tend more and more to go over to the
region of short wave-lengths and high frequencies, and this shifting
would apparently go on indefinitely. The theory thus leads to results
which are not only in disagreement with experiment, but which must be
looked upon as extremely unreasonable in themselves.
Planck, however, had vanquished these difficulties and had obtained a
radiation law in agreement with experiment by introducing an extremely
curious hypothesis. Like Lorentz, he thought of radiation as produced
through the medium of small vibrating systems or oscillators, which
could emit or absorb rays of a definite frequency ν. But while,
according to the Lorentz theory and the classical electrodynamics,
radiation can be emitted in infinitely small quantities (_i.e._
small without limit), Planck assumed that an oscillator can emit and
absorb energy only in certain definite quantities called _quanta_,
where the fundamental quantum of radiation is dependent on the
frequency of the oscillator, varying directly with the latter. If
thus we denote the smallest quantity of energy which an oscillator of
frequency ν can emit or absorb by E, then we can write
E = _h_ν,
where _h_ is a definite constant fixed for all frequencies.
Accordingly the cavity can receive radiation energy of frequency ν
from the radiating oscillators in its wall, or transfer energy to
these in no smaller quantity than _h_ν. The total energy of that
kind emitted or absorbed at any given time will always be an integral
multiple of _h_ν. Oscillators with a frequency 1½ times as great
will emit energy in quanta which are 1½ times larger, and so on.
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