The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
For the innermost stationary orbit, for which _n_ = 1, the
ionizing work A₁ will accordingly be equal to the product of the
constants _h_ and K of Planck and Balmer respectively; and for the
orbits No. 2, No. 3, No. 4, etc., the values will be respectively ¼,
¹/₉, ¹/₁₆, etc., of this product. From the charges on the nucleus and
the electron, which are both equal to the elementary quantum _e_
of electricity (see p. 90), and from the ionizing energy for a given
orbit we can now find by the use of simple mechanical considerations
the radius of the orbit. If we denote the radii of the orbits 1, 2,
3 ... by _a_₁, _a_₂, _a_₃ ..., we then obtain for the
diameters 2_a_₁, 2_a_₂, 2_a_₃ ... the values 2_a_₁
= 1·056 × 10⁻⁸ cm. (or approximately 2_a_₁ = 10⁻⁸ cm.), 2_a_₂
= 4 × 10⁻⁸ cm., 2_a_₃ = 9 × 10⁻⁸ cm., etc. It is seen that the
radii of the orbits are in the proportion 1, 4, 9 ..., or in other
words the squares of the integers which determine the orbit numbers. It
is in this proportion that the circles in Fig. 25 are drawn. We must
remember, however, that we have here for the moment been thinking of
the orbits as circles, while in reality they must in general be assumed
to be ellipses. The foregoing considerations will, however, still hold
with the single change that 2_a_ₙ will now mean, instead of the
diameter of a circle, the major axis of an ellipse.
Let us return to the formulæ
Aₙ″ Aₙ′
ν = ----- - ----
_h_ _h_
K K
and ν = ------ - -----
_n″_² _n′_²
Here _n″_ denotes in the first formula the index number for the
_inner_ of the two orbits between which the transition is supposed
to take place, while in the second formula _n″_ denotes a definite
series in the hydrogen spectrum. If _n″_ is 2 while _n′_
takes on the values 3, 4, 5 ... ∞ then in the Bohr model of the
hydrogen atom this corresponds to a series of transitions _to_ the
orbit No. 2 _from_ the orbits 3, 4, 5 ..., while in the hydrogen
spectrum this corresponds to the lines in the Balmer series, namely,
the red line (Hα) corresponding to the transition 3-2, the blue-green
line (Hβ) to 4-2, the violet line (Hγ) to 5-2 and so on. If we now put
_n″_ = 1 while _n′_ takes the values 2, 3, 4 ..., we get in
the atom transitions to the orbit No. 1 from the orbits No. 2, 3, 4
..., corresponding in the spectrum to what is called the Lyman series
in the ultra-violet (named after the American physicist Lyman, who
has carried on extensive researches in the ultra-violet region of the
spectrum). Thus every line in the hydrogen spectrum is represented by a
transition between two definite stationary states in the hydrogen atom,
since this transition will give the frequency corresponding to the line
in question.
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