The Birth-Time of the World and Other Scientific EssaysJoly, John
Science
The Birth-Time of the World and Other Scientific Essays
Joly, John
Science
With this much to go upon, and the important additional fact that
the electronic discharge--as from the X-ray tube or from
radium--generates the latent image, I think we are fully entitled
to suggest, as a legitimate lead to experiment, the hypothesis
that the beginnings of photographic action involve an electronic
discharge from the light-sensitive molecule; in other words that
the latent image is built up of ionised atoms or molecules the
result of the photo-electric effect on the illuminated silver
haloid, and it is upon these ionised atoms that the chemical
effects of the developer are subsequently directed. It may be
that the liberated electrons ionise molecules not directly
affected, or it may be that in their liberation they disrupt
complex molecules built up in the ripening of the
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emulsion. With the amount we have to go upon we cannot venture to
particularise. It will be said that such an action must be in
part of the nature of a chemical effect. This must be admitted,
and, in so far as the rearrangement of molecular fabrics is
involved, the result will doubtless be controlled by temperature
conditions. The facts observed by Sir James Dewar support this.
But there is involved a fundamental process--the liberation of the
electron by the electric force in the light wave, which is a
physical effect, and which, upon the hypothesis of its reality as
a factor in forming the latent image, appears to explain
completely the outstanding photographic sensitiveness of the film
at temperatures far below those at which chemical actions in
general cease.
Again, we may assume that the electron--producing power of the
special sensitiser or dye for the particular ray it absorbs is
responsible, or responsible in part, for the special
sensitiveness it confers upon the film. Sir Wm. Abney has shown
that these sensitisers are active even if laid on as a varnish on
the sensitive surface and removed before development. It must be
remembered, however, that at temperatures of about -50 deg. these
sensitisers lose much of their influence on the film; as I have
pointed out in a paper read before the Photographic Convention of
1894.
It. appears to me that on these views the curious phenomenon of
recurrent reversals does not present a problem hopeless of
explanation. The process of photo-
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