The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
I further claim, as an entirely new manufacture, the sheet caoutchouc
prepared by the within described process of treatment, by the metallic
solutions as herein described, as it is thereby so essentially changed
in its properties as to bear but little resemblance to such articles as
have, heretofore, been manufactured out of the same material, and is
rendered applicable to a variety of new purposes hitherto unattempted,
or attempted without success.
_Nineteenth_, to Stephen C. Smith, New York, December 7th, 1837.
Manufacture of India-rubber.
_Twentieth_, to Charles Goodyear, Roxbury, Mass., July 24th, 1838. For
manufacturing India-rubber.
_Twenty-first_, to Nathaniel Hayward, Assigner to Charles Goodyear,
Boston, Mass., Feb. 24th, 1839. For an Improvement in the mode of
preparing India-rubber for the manufacture of various articles.
Sulphur, it is known, is soluble in the essential oils, which also are
the solvents usually employed for dissolving caoutchouc, the oil of
turpentine being generally employed for that purpose. I take the
essential oil, say oil of turpentine, and dissolve in it, by digestion,
a portion of sulphur generally using about a teaspoonful of sulphur, in
flour, to a quantity of oil of turpentine which is to dissolve a pound
of India-rubber; the exact proportion not being important, and that
indicated being sufficiently near for practical purposes. With this
solution I proceed as with the ordinary spirits of turpentine.
Instead of making this solution of sulphur, I sometimes use the flour of
sulphur, or sulphur in fine powder, and incorporate it in the proportion
above indicated with the gum when brought to a pulpy mass by any of the
common solvents, or when worked by heated cylinders without any
solvents, taking care that it is intimately mixed with the mass. Another
mode of using the sulphur is to apply it to the surface of the gum after
it has been applied to the cloth, or rolled into sheets, causing it to
adhere by pressure or otherwise. After which the gum is to be submitted
to the action of metallic salts, in the manner described by Charles
Goodyear.
The effect of the sulphur in whatever way it may be added to the gum, is
to cause it to dry more perfectly, and to improve the whole substance
thereof, rendering it much superior to that prepared by any other
combination therewith. The subsequent process of curing, or tanning, the
surface above referred to, as patented by Charles Goodyear, removes all
the odor of sulphur, and is intended to be generally applied to all
articles manufactured as above.
What I claim as my invention, and desire to secure by letters patent, is
the combining of sulphur with gum elastic, whether in solution or in
substance, in either of the modes above pointed out, or in any other
that is substantially the same, and which will produce a like effect.
Public-domain text, read in full here on John Shaqi.
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