The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
REMARKS.—Two patents for improvement in the manufacture of India-rubber,
were granted in 1850. The first of which is for the use of the
hypo-sulphate of zinc. This salt is prepared in the following manner. In
a solution of caustic lime, potash, or other caustic alkali, boil flour
of sulphur until the liquor is saturated, and into this liquid pass
sulphurous acid gas, by any of the known means, for the purpose of
obtaining a hypo-sulphate of the alkaline base. The liquid is allowed to
stand and cool. The clear liquor is then decanted into a vessel
containing a suitable quantity of a saturated solution of the nitrate or
other analogous salt of zinc. On mixing these solutions the zinc is
precipitated in a white powder, which is regarded as the hypo-sulphate
of zinc. It is then washed on a filter, dried and subsequently ground in
a paint-mill. Three pounds of this powder is mixed with ten pounds of
India-rubber, and heated from three to five hours, at a temperature of
260° to 280°. The rubber, according to the inventor, will be found
completely cured or vulcanized, and requires no free sulphur to be used
in any part of the process, and no washing with alkali, as do the
ordinary materials used for vulcanizing. Hence it is alleged that this
process is adapted to the covering of silks and other delicate textures,
and colored fabrics.
Another patent was granted for a compound for vulcanizing India-rubber.
The mode of treatment is much the same as the last, and produces the
same results. The material is the artificial bi-sulphuret of zinc. The
inventor claims the use of this composition _without the use of sulphur_
in any part of the process of manufacture, and the washing with alkaline
solutions is not required, and is not used in this mode of manufacture.
_Fifty-ninth_, to Fowler M. Ray, New York, Oct. 18, 1850. For vulcanized
India-rubber springs. The “claim” as set forth in the employment of a
ring, or rings, or disks, made of any of the preparations of caoutchouc,
known under the various appellations of metallic or vulcanized rubber,
as a substitute for metal or other kinds of springs, heretofore known
and used, when such ring or rings, or disk or disks, or the equivalent
thereof are applied, in manner substantially as described, whether made
of metal or other solid or non-elastic substance. Also making the
surfaces of all or either of the plates above and below, and interposed
between the elastic rings or their equivalents, or the surfaces of the
elastic rings or other of their convex, substantially in the manner and
for the purpose specified.
_Sixtieth_, to Jonathan Trotter, of New York, Dec. 3, 1850. For
vulcanizing India-Rubber. The claim is the use and employment of zinc,
in a manner whereby a hypo-sulphate or similar preparation of zinc is
obtained in combination with India-rubber, for the purpose of curing or
vulcanizing it, substantially as set forth with the use of free sulphur
in any way in combination with the rubber.
Public-domain text, read in full here on John Shaqi.
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