The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
It requires several days and sometimes weeks to effect these several
objects, by the use of lime alone. Moreover, lime being nearly
insoluble, the hides become impregnated therewith, so that bates and
drenches and much labor are required to remove it, before the hides are
in a suitable condition to receive the tannin, in consequence of which,
their muscular fibre and texture are materially injured. But potash
being very soluble, is easily washed or worked out by water alone;
besides, it has a greater affinity for fat or oil, and makes a soluble
soap, which is also easily worked out; but lime makes an insoluble soap,
which is removed with more difficulty; potash being soluble, penetrates
and softens the hide more speedily, and thus enables the lime itself to
act sooner than it could alone. But fresh quick lime loosens hair sooner
than potash. Thus the two conjoined, subserve a better purpose than
either singly.
Salt, in solution, also aids in softening dry or hard hides. It protects
the substance of the hide from the too caustic action of the
alkalies—loosens dirt, grease, &c., and thereby purifies the skin. It
might be omitted in treating salted hides unless soaked too long in
water. But in all cases it preserves the substance and weight of the
hides, while undergoing the liming process.
Second, the nature of Hibbard’s invention, so far as it relates to the
process of tanning, consists in the use of a composition of salt,
sulphuric acid, and sumac, oak, hemlock bark, or any other tannin used
for tanning.
The salt, sulphuric acid, and tannin being mixed together in water, in
certain proportions hereafter mentioned, a portion of the salt is
decomposed by the sulphuric acid, forming sulphate of soda and setting
the muriatic acid free, which (the muriatic acid) being absorbed by the
water acts directly and rapidly on whatever of the alkalies may yet
remain in the skins, dissolving and removing them, while it acts with
equal rapidity on the hide itself, “raising it,” or opening its pores,
prepares it to receive the tannin, which, being present also in the
mixture, immediately unites with the gelatine of the hide, forming
leather more expeditiously than by the old method.
To enable others skilled in the art of tanning to use this method, let
them observe the following:
For unhairing and liming, so called, and for pulling wool, prepare and
use the following composition, which we denominate—
Composition No. 1.—Good wood ashes, 1 bushel (or potash about 5 pounds);
fresh slaked lime 4 quarts; salt about 3 quarts; water about 100
gallons.
These ingredients may be mixed together and the hides be put into the
mixture, for unhairing and liming. But for pulling wool, take lime and
ashes equal parts, and salt 1 quart, to one bushel of the mixture and
mix with water sufficient to make a thin paste, which is to be applied
to the flesh sides of the skins in the usual way, and kept at a
temperature of 60° to 68° F.
Public-domain text, read in full here on John Shaqi.
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