The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
Messrs. Mackintosh & Co., claim in their patent for vulcanizing all the
preparations of sulphur, and without it, so far as I know and believe,
no substitute has yet, or is likely to be discovered at a price which
can render it commercially available. Indeed, I doubt whether any other
than sulphurous bodies will vulcanize, or render fit for the use of the
engineers the gum called India-rubber. Hence, the reason why many of the
manufacturers are licensed under that firm, and subject to have their
goods so stamped. The American inodorous makers attempted to shield
themselves, (but on legally trying the point) in vain. The screen
against Mr. Mackintosh’s patent was called, as a blind, “hypo.” It is
prepared in several ways, but is a compound of sulphur and lead, and
when perfect and the lime well washed away, is a very excellent black,
costing about 30_s._ per cwt.; but its whole efficacy rests with the
sulphur, and without it would not vulcanize, (though lead works kindly
with caoutchouc). This chemical contains about 20 per cent., of sulphur,
consequently, five pounds is about equal to twenty-five ounces of
sulphur. This extra cost was readily submitted to, rather than to
knuckle under to Messrs. Mackintosh’s patent. In many cases it was only
said to be used, and what really was used, was white lead or lampblack,
oxide of zinc, all in connection with sulphur, according as the color of
the goods required, rendered necessary. It was pretended also, by these
inodorous manufacturers, that white goods, such as the elastic beds,
advertised as “Improved Hydrostatic Beds,” and “Hospital Sheeting,” were
vulcanized with sulphuret of zinc, prepared chemically; when, in fact,
it is well known that the cost of manufacture is quite prohibitory, and
is only of value in proportion to its richness in sulphur. What was in
reality used, was, and is, the “yellow sulphur,” and the “pure
precipitate of that article.” I mention these things to clear the
mystification it may be to the interest of manufacturers to keep up, and
as I only write from experience, I have reason to believe your readers,
who are interested, will better understand the nature and value of
unmixed and mixed caoutchouc, after my fund on this topic is exhausted.
With these remarks I will give the recipe for common black packing at
2_s._ 2_d._ per lb., in quantity, discount as agreed.
The chemical termed “hypo” is manufactured thus: The sugar of lead is
made into a solution with water in a separate vessel. The sulphur and
lime are then boiled in water, so as to make a solution of sulphur with
the lime. The latter solution (clear) is then poured into the former,
which unites with the sulphur, and the precipitate is the “hypo.” The
hypo is then washed and dried. The lime merely enables the lead to take
up the sulphur.
Public-domain text, read in full here on John Shaqi.
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