In some siliceous nodules which now lie before me, the external crust for about the tenth of an inch consists of white agate, in others it is much thinner, and in some much thicker; corresponding with this crust there are from twenty to thirty superincumbent strata, of alternately darker and lighter colour; whence it appears, that the external crust as it cooled or froze, propelled from it the iron or manganese which was dissolved in it; this receded till it had formed an arch or vault strong enough to resist its further protrusion; then the next inner sphere or stratum as it cooled or froze, propelled forwards its colouring matter in the same manner, till another arch or sphere produced sufficient resistance to this frigoriscent expulsion. Some of them have detruded their colouring matter quite to the centre, the rings continuing to become darker as they are nearer it; in others the chalybeate arch seems to have stopped half an inch from the centre, and become thicker by having attracted to itself the irony matter from the white nucleus, owing probably to its cooling less precipitately in the central parts than at the surface of the pebble. A similar detrusion of a marly matter in circular arches or vaults obtains in the salt mines in Cheshire; from whence Dr. Hutton very ingeniously concludes, that the salt must have been liquified by heat; which would seem to be much confirmed by the above theory. Edinb. Transact. Vol. I. p. 244. I cannot conclude this account of Scots-pebbles without observing that some of them on being sawed longitudinally asunder, seem still to possess some vestiges of the cylindrical organization of vegetables; others possess a nucleus of white agate much resembling some bulbous roots with their concentric coats, or the knots in elm-roots or crab- trees; some of these I suppose were formed in the manner above explained, during the congelation of masses of melted flint and iron; others may have been formed from a vegetable nucleus, and retain some vestiges of the organization of the plant. 4. SAND OF THE SEA. The great abundance of siliceous sand at the bottom of the ocean may in part be washed down from the siliceous rocks above described, but in general I suppose it derives its acid only from the vegetable and animal matter of morasses, which is carried down by floods or by the atmosphere, and becomes united in the sea with its calcareous base from shells and coralloids, and thus assumes its crystalline form at the bottom of the ocean, and is there intermixed with gravel or other matters washed from the mountains in its vicinity. 5. CHERT, OR PETROSILEX.