The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
[Illustration: Fig. 124. A A. Board to which B B is fixed. O. Oxygen
pipe. H. Hydrogen pipe. C C. Space filled with wire gauze. D. Lime
cylinder.]
[Page 125]
_Seventeenth Experiment._
There are many circumstances that will cause the union of oxygen and
hydrogen, which, if confined by themselves in a glass vessel, may be
preserved for any length of time without change; but if some powdered
glass, or any other finely-divided substance with sharp points, is
introduced into the mixed gases at a temperature not exceeding 660°
Fahrenheit, then the gases silently unite and form water.
This curious mode of effecting their combination is shown in a still
more interesting manner by perfectly clear platinum foil, which if
introduced into the mixed gases gradually begins to glow, and becoming
red-hot causes the gases to explode. Or still better, by the method
first devised by Dobereiner, in 1824, by which finely prepared spongy
platinum--_i.e._, platinum in a porous state, and exposing a large
metallic surface--is almost instantaneously heated red-hot by contact
with the mixed gases. When this fact became known, it was further
applied to the construction of an instantaneous light, in which hydrogen
was made to play upon a little ball of spongy platinum, and immediately
kindled. These Dobereiner lamps were possessed by a few of the curious,
and would no doubt be extensively used if the discovery of phosphorus
had not supplied a cheaper and more convenient fire-giving agent. When
the spongy platinum is mixed with some fine pipeclay, and made into
little pills, they may (after being slightly warmed) be introduced into
a mixture of the two gases, and will silently effect their union. The
theory of the combination is somewhat obscure, and perhaps the simplest
one is that which supposes the platinum sponge to act as a conductor of
electric influences between the two sets of gaseous particles; although,
again, it is difficult to reconcile this theory with the fact that
powdered glass at 660°, a bad conductor of electricity, should effect
the same object. The result appears to be due to some effects of surface
by which the gases seem to be condensed and brought into a condition
that enables them to abandon their gaseous state and assume that of
water.
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