The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
With respect to No. 3, Mr. William Crookes has shown, that when a
saturated solution of gallic acid is required in large quantities, that
it is better to dissolve at once two ounces of gallic acid in six ounces
of alcohol (60° over proof); to hasten solution, the flask may be
conveniently heated by immersion in hot water; when cold it should be
filtered, mixed with half a drachm of glacial acetic acid, and preserved
in a stoppered bottle for use; so prepared it will keep unaltered for a
considerable length of time. The gallic acid is not precipitated from
this solution by the addition of water; consequently, if in any case
desirable, the development of a picture may be effected with a much
stronger bath than the one usually employed. To obtain a solution of
about the same strength as a saturated aqueous solution, such as No. 3,
half a drachm of the alcoholic solution is mixed with two ounces of
water; but for my particular purpose, says Mr. Crookes, referring to the
wax-paper process, "I prefer a weaker bath, which is prepared by mixing
half a drachm with ten ounces of water." In either case it [Page 143]
will be found necessary to add solution of nitrate of silver in small
quantities, as the developing picture seems to require it.
Returning again to the solutions marked 1, 2, 3, the numbers will assist
the memory in mixing the proportions of each. If the paper is required
to be used _at once_, a drachm of each may be mixed together and spread
over the iodized paper (of course, in a dark room), which is then
transferred to a clean blotting-book of white bibulous paper, and being
placed in the paper-holder may be taken to the camera and exposed at
once. If the paper is not required to be used immediately, the solutions
are mixed in the proportions of the numbers--viz., one of No. 1, two of
No. 2, three of No. 3; and in making the mixture, it is advisable to
keep a measure specially for No. 3, the gallic acid, or else the
measure, if used for the three solutions, will have to be washed out
every time, which is very troublesome, particularly where water is not
plentiful.
If the excited paper is required to be kept some hours before use, No. 3
must be added in still larger proportion, as much as ten or even twenty
measures of No. 3 to two of No. 2, and one of No. 1, being used, and
even this large dilution is frequently insufficient to prevent the paper
spoiling in hot weather; therefore if the temperature is high, too much
reliance must not be placed on this paper, as it is peculiarly
disappointing, after walking some miles to romantic and beautiful
scenery, to find, when developing the pictures in the evening, that the
paper used was all spoilt before exposure; and it will be seen presently
that when the excited paper is to be carried about for use, it is better
to adopt the wax-paper process.
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