The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
[Illustration: Fig. 143. First effect of peripatetic photography on the
rural population.]
[Page 149]
BROMINE.
Bromine ([Greek: _brômos_], a bad odour). Symbol, Br. Combining
proportion, 80. Specific gravity, 2.966.
In a previous portion of this work, the connexion between chlorine,
iodine, and bromine has been pointed out; and as we have to notice the
colour of the element bromine, the chromatic union of the triad may be
alluded to. These elements present very nearly all the colours of the
spectrum:
Bromine red to orange.
Chlorine yellow to green.
Iodine blue, indigo, violet.
These three elements also furnish examples of the three conditions of
matter; iodine being a solid, bromine a fluid, chlorine a gas; the
relation of their combining proportions is also curious: as might be
expected, the fluid bromine takes an intermediate position, and
(according to the axiom that half the sum of the extremes is equal to
the mean) by dividing the combining proportions of iodine and chlorine,
and adding them together, we have, as nearly as possible, the combining
proportion of bromine:
Chlorine 35 ÷ 2 = 17.75
Iodine 126 ÷ 2 = 63
-----
80.75
The combining proportion of bromine is 80, but 80.75 is so near, that it
may reasonably be conjectured future experiments will reduce the number
of the three elements, and may prove that they are only modifications of
a single one. This is the only kind of alchemy which is tolerated in the
nineteenth century, and any philosopher who will reduce the number of
elements, and prove that some of them are only modifications of others,
will achieve a renown that must transcend the _éclat_ of all previous
discoverers.
Bromine was discovered by Balard, in 1826, and, like chlorine and
iodine, is a constituent of sea water. The chief source of bromine is a
mineral spring at Kreutznach, in Germany. The process by which it is
obtained offers a good example of chemical affinity; the water of the
mineral spring is evaporated, all crystallizable salts removed, and a
current of chlorine gas passed through the remaining solution, which
changes to a yellow colour, in consequence of the liberation of the
bromine by the combinations of chlorine with the bases previously united
with the former; the liquid is then shaken with ether, which dissolves
out the bromine. In the next place, the etherial solution is agitated
with strong solution of potassa, and is thus obliged to part with the
bromine which is converted into bromate of potassa; this is ultimately
changed by fusion to bromide of potassium; and by distillation with
black oxide of manganese and sulphuric acid, the bromine is finally
obtained. Six [Page 150] processes are therefore necessary before the
small quantity of bromine contained in the mineral spring-water, is
separated.
_First Experiment._
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