The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Symbol, S; combining proportion, 16.
Sulphur, like charcoal, is of common occurrence in nature, and is
chiefly supplied from the volcanic districts of Tuscany and Sicily:
there is an abundance of this element in the United Kingdom, but then it
is locked up in combination with iron, copper, and lead, under the name
of iron pyrites, copper pyrites, galena; and whilst Sicily and Tuscany
supply thousands of tons weight in the uncombined state, it is not, of
course, worth while to go through expensive operations at home for the
separation of sulphur from the ores. During the dispute between Sicily
and England, several patents were secured for new and economical
processes by which sulphur was obtained from various minerals; and had
this country been excluded from a supply of native sulphur, no doubt
some of these patents would now be in active operation.
It is almost possible to estimate the commercial prosperity of a country
by the sulphur it consumes, not, happily, by their warlike operations,
but in the manufacture of oil of vitriol or sulphuric acid, which is the
starting point of a great number of useful arts and manufactures.
_First Experiment._
Some very curious results may be obtained by heating sulphur at certain
temperatures; in the ordinary state it is a pale yellow solid, and when
subjected to a temperature of 226° Fahr. it melts to a brownish-yellow,
transparent, thin fluid; according to all preconceived notions of the
properties of substances which liquify by an increase of heat, it might
be imagined that every additional degree of heat would only [Page 163]
render the melted sulphur still more liquid, but strange to say, when it
reaches a temperature of about 320° Fahr. it changes red, and thick like
treacle; and as the heat rises it becomes so tenacious, that the ladle
in which it is contained may be inverted, and the sulphur will hardly
flow out: at about 482° Fahr. it again becomes liquid, but not so fluid
as at the lower temperature. If allowed to cool from 482° Fahr., the
above results are simply inverted; the sulphur becomes thick, again
liquid, and finally crystallizes in long, thin, rhombic prisms, which
are seen most perfectly by first allowing a crust of sulphur to form on
the liquid portion, and then having made two holes in this crust, the
sulphur is poured out, when the remainder is found in the interior of
the crucible crystallized in the form already mentioned. Sulphur takes
fire in the air when exposed to a heat of about 560° Fahr., and burns
with a pale blue flame; and, as already stated, it may be poured from a
considerable height on a still dark night, and produces a continuous
column of blue fire, just like an unbroken current of electricity. If
the melted and burning sulphur is received into a vessel containing
boiling water, it is no longer yellow, but assumes a curious
_allotropic_ state, in which it is a reddish-brown, transparent,
shapeless mass, that may be easily kneaded and used for the purpose of
Public-domain text, read in full here on John Shaqi.
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