The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Sulphuric acid, HO,SO_{3}, or oil of vitriol, is made in such enormous
quantities that it is never worth while to attempt its preparation on a
small scale. In consequence of its great affinity for water, many
energetic changes are produced by its action. Oil of vitriol poured on
some loaf sugar placed in a breakfast-cup with the addition of a
dessert-spoonful of boiling water, rapidly boils and deposits an
enormous quantity of black charcoal. If a word be written on a piece of
white calico with dilute sulphuric acid, and then rapidly and thoroughly
washed out, no visible change occurs; but if the calico is exposed to
heat, so that the excess of water is driven off, the remaining and now
concentrated oil of vitriol attacks the calico, and the word is
indelibly printed in black by the decomposition of the fabric of cotton.
A very remarkable process has lately been introduced by Mr. Warren de la
Rue, by which paper is converted into a sort of tough parchment-like
material, called ametastine, by the action of oil of vitriol and water
of a certain fixed strength; and any departure from the exact
proportions destroys the toughness of the paper. After the paper has
been acted upon by the acid, it becomes extremely tenacious, and will
support a considerable weight without breaking. Mr. Smee has used this
ametastine in the construction of an hygrometer, and states that it may
save many a traveller from catching a severe rheumatism in a damp bed.
_Sixth Experiment._
When the vapour of sulphur is passed over red-hot charcoal and the
product carefully condensed, a peculiar liquid is obtained, called
bisulphide of carbon (CS_{2}), which possesses a peculiar odour, is
extremely transparent and brilliant-looking, and enjoys a high
refractive power. This liquid is used as a solvent for phosphorus and
other substances, and is extremely volatile and combustible, and burns
silently with a pale blue flame. The combustion of its vapour, mixed
with certain gases, offers a good example of the fact that slow burning
may be a peaceful experiment, whilst very rapid combustion often
resolves itself into an explosion. Thus, if a few drops of bisulphide of
carbon are dropped into a narrow-mouthed dry quart bottle containing
common air, and flame applied, the combustion takes place with rapidity,
a rushing or [Page 165] roaring sound being audible, in consequence of
the diffused vapour being supplied with more oxygen, and burning more
rapidly than it would do if simply consumed from a stick or glass rod
wetted with the fluid. A still greater rapidity of combustion is ensured
by dropping some bisulphide of carbon into a long stout cylindrical jar,
fifteen inches long and three inches in diameter, containing nitric
oxide gas (NO_{2}); when flame is applied the mixture burns with a
bright flash and some noise, and if burnt in a narrow mouthed bottle
would most likely blow it to atoms.
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