The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
This element, formerly sold at four or five shillings the ounce, has now
fallen so much in price, from the greater demand and larger production,
that it may be bought for a few shillings the pound, and is imported in
tin cases in large quantities from Germany. It was discovered about two
hundred years ago by Brandt, a merchant of Hamburg, and may be prepared
on a small scale by distilling at a red heat phosphoric acid previously
fused with one-fourth of its weight of powdered charcoal.
_First Experiment._
Phosphorus, when pure, is without taste or colour, but generally of a
very pale buff-colour, and semi-transparent; it is extremely
combustible, and is usually preserved under the surface of water; when
perfectly dry, a thin slice will take fire at 60° Fah., and burns with
great brilliancy. Considering the heat produced during the combustion of
phosphorus, it might be thought that it would infallibly set fire to any
ordinary combustible, such as paper or wood, but this is not the case
when phosphorus is employed by itself, as may be proved by the following
experiment.
Cut five very small pieces of phosphorus, and place them like the five
of diamonds on a sheet of cartridge-paper laid upon the table, set the
bits of phosphorus on fire, when they will be rapidly burnt away [Page
167] leaving only five black spots, but not firing the paper, as would
be the case if some red-hot coals or charcoal were placed in the same
position. The cause is very simple. Phosphorus in burning produces
phosphoric acid, which is an anti-combustible, and coats the surface of
the paper round the spot where the combustion occurs, and acting as a
kind of glaze or glass, excludes the oxygen of the air, and prevents the
fire spreading.
If some powdered sulphur is sprinkled round the spot where the bit of
phosphorus is to be burnt, the case is very different; the heat melts
and sets fire to the sulphur, which being uncoated with the phosphoric
acid, communicates to the paper; and it is on this principle that
lucifer-matches can be used as instantaneous lights. The tip of the wood
of which they are composed is first dipped in sulphur, and then the
phosphorus composition made of gum, chlorate of potash, vermilion, and
phosphorus, is placed over it; and if the latter were used alone without
the sulphur, not one match in a hundred would take fire properly.
_Second Experiment._
Public-domain text, read in full here on John Shaqi.
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