The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
The similarity in composition, though not in outward form, is further
shown by filling two jars with oxygen gas, and having provided two
deflagrating spoons, some common phosphorus is placed in one, and red
phosphorus in the other; a wire, gently heated by dipping it into some
boiling water, is now applied to the former, which immediately takes
fire, and may be plunged into the jar of oxygen gas, when it burns with
the usual brilliancy. The red phosphorus, however, must be brought to a
much higher temperature (500° Fah.) before it will even shine in the
dark, and then with a still further increase of heat it takes fire, and
on being placed in the other jar of oxygen burns up much more slowly
than the yellow phosphorus, but at last exhibits that brilliant flash of
light which is so characteristic of the combustion of phosphorus in
oxygen.
The amorphous or red phosphorus is employed in the manufacture of
_safety chemical matches_, and M. A. Meunons has secured a patent in
England for an improvement in lucifer matches, with a view to obviate
the risks of accidental ignition. To attain this end the matches are
first cut by a machine from cubes of wood, the cut being stopped at a
short distance from the end of each cube, so as to leave the lower
extremities adherent. The upper or free extremity of each packet of
splints thus formed being coated with wax or sulphur, is dipped in one
of the following preparations:--Chlorate of potash, two parts;
pulverized charcoal, one part; umber, one part; or, chlorate of potash,
sulphur, and umber, in equal parts, thoroughly mixed with glue. The
opposite extremity or "cut" of each packet is then painted over with
amorphous phosphorus blended with size, so that on separating the
matches the phosphorus is only found on the top of each. The matches
thus prepared are ignited by breaking off a small piece of the
phosphorised end and rubbing it on the opposite extremity covered with
the inflammable preparation.
Loud exploding and dangerous lucifers were formerly made by dipping
bundles of matches, previously coated with sulphur at the tips, into a
thick solution of gum, at a temperature of 104° Fahr., coloured with
smalt or red lead, in which was dissolved a certain proportion of
chlorate of potash, and also containing finely divided particles of
phosphorus obtained by the constant stirring and rubbing of the
materials in a mortar. When dry the matches exploded if rubbed against a
gritty surface, and there was always a risk of a fragment flying off and
entering the eye. To obviate this danger, _silent_ or _noiseless lucifer
matches_ were invented, and the composition used (according to Böttger)
is as follows:--Gum arabic, 16 parts by weight; phosphorus, 9 parts;
nitre, 14 parts; powdered black oxide of manganese, 16 parts. The above
ingredients are worked up in a mortar with water, at 104° Fahr., and the
matches previously tipped with sulphur are dipped therein and afterwards
dried.
[Page 169]
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