The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
It is by "chemical action" the electricity is produced, and as action
and reaction are always equal, but contrary, we are not surprised to
find that the electricity from the voltaic battery will in its turn
decompose chemically many compound bodies, of which water is one of the
most interesting examples. It was in the year 1800, and immediately
after Volta's announcement to Sir Joseph Banks of his discovery of the
pile, that Messrs. Nicholson and Carlisle constructed the first pile in
England, consisting of thirty-six half-crowns, with as many discs of
zinc and pasteboard soaked in salt water. These gentlemen, whilst
experimenting with the pile, observed that bubbles of gas escaped from
the platinum wires immersed in water and connected with the extremities
of the Volta's pile, and covering the wires with a glass tube full of
water, on the 2nd of May, 1800, they completed the splendid discovery of
the fact that the Volta's current had the power to decompose water and
other chemical compounds.
[Page 198]
In 1801, Davy had succeeded to a vacant post in the Royal Institution,
and on Oct. 6th, 1807, made his transcendent discovery of potassium with
the aid of the voltaic battery, and from that and other experiments
inferred that the whole crust of the globe was composed of the oxides of
metals. To exhibit the decomposition of water, two platinum plates with
proper connecting wires, passing to small metallic cups full of mercury,
are cemented inside a glass vessel, which is then filled with dilute
sulphuric acid. Just above the platinum plates and over them, stand two
glass tubes also containing the same fluid in contact with the battery.
Two measures of hydrogen are found in one tube, and one of oxygen in the
other. (Fig. 183.)
[Illustration: Fig. 183. A A. A finger glass with two holes drilled to
pass the wires through, which are imbedded in cement up to the platinum
plates. B B. Glass tubes, closed at one end and open at the other, which
are placed over the platinum plates to receive the liberated oxygen and
hydrogen. The scale at the side shows the respective volumes of two of H
to one of O.]
To measure the quantity power of the voltaic battery, an important
instrument invented by Faraday is used. It consists of separate platinum
plates cemented in a wooden stand, and over which a capped air-jar with
a bent pipe is also cemented. This apparatus contains dilute sulphuric
acid of the same strength as that used in the battery under examination,
and by taking the time, the quantity of the mixed oxygen and hydrogen
gases producible by a battery per minute is accurately determined, the
gases of course being collected in a graduated jar. (Fig. 184.)
[Illustration: Fig. 184. A. Gas jar with cap and bent tube passing to
the graduated tube C; the jar is cemented in the same stand which
carries the connecting cups, wires, and platinum plates, which are bent
round each other to improve the action of the voltameter.]
[Page 199]
_Fifth Experiment._
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