The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
[Illustration: Fig. 109. A. Gas jar divided into five equal parts. B B.
Section of pneumatic trough, to show the decantation of gas from one
vessel to another. The gas is being passed from C to A, through the
water.]
[Page 107]
HYDROGEN.
Hydrogen ([Greek: _udôr_], water; [Greek: _gennaô_], I give rise to), so
termed by Lavoisier--called by other chemists inflammable air, and
phlogiston. Symbol, H; combining properties, 1. The lightest known form
of matter.
Every 100 parts by weight of water contain 11 parts of hydrogen gas; and
as the quantity of water on the surface of the earth represents at least
two-thirds of the whole area, the source of this gas, like that of
oxygen or nitrogen, is inexhaustible. Van Helmont, Mayow, and Hales had
shown that certain inflammable and peculiar gases could be obtained, but
it was reserved for the rigidly philosophic mind of Cavendish to
determine the nature of the elements contained in, and giving a
speciality to, the inflammable gases of the older chemists. By acting
with dilute acids upon iron, zinc, and tin, Cavendish liberated an
inflammable elastic gas; and he discovered nearly all the properties we
shall notice in the succeeding experiments, and especially demonstrated
the composition of water in his paper read before the Royal Society in
the year 1784.
_First Experiment._
Hydrogen is prepared in a very simple manner, by placing some zinc
cuttings in a bottle, to which is attached a cork and pewter or bent
glass tube, and pouring upon the metal some dilute sulphuric or
hydrochloric acid. Effervescence and ebullition take place, and the gas
escapes in large quantities, water being decomposed; the oxygen passes
to the zinc, and forms oxide of zinc, and this uniting with the
sulphuric acid forms sulphate of zinc, which may be obtained after the
escape of the hydrogen by evaporation and crystallization. (Fig. 110.)
Zn + HO.SO_{3} = ZnO.SO_{3} + H;
or,
Zn + HCl = ZnCl + H.
In nearly all the processes employed for the generation of hydrogen gas,
a metal is usually employed, and this fact has suggested the notion that
hydrogen may possibly be a metal, although it is the lightest known form
of matter; and it will be observed in all the succeeding experiments
that a metallic substance will be employed to take away the oxygen and
displace the hydrogen.
[Illustration: Fig. 110. A. Bottle containing zinc cuttings and water
and fitted with a cap and two tubes, the one marked B, containing a
funnel, conveys the sulphuric acid to the zinc and water, whilst the gas
escapes through the pipe C.]
[Page 108]
Whenever hydrogen is prepared it should be allowed to escape from the
generating vessel for a few minutes before any flame is applied, in
order that the atmospheric air may be expelled. The most serious
accidents have occurred from carelessness in this respect, as a mixture
of hydrogen and air is explosive, and the more dangerous when it takes
fire in any closed glass bottle.
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