The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
Those of my readers who are sufficiently interested in this subject to
care to study it practically should make the following experiment:
Dissolve in distilled water, or, better, in water slightly acidulated
with hydrochloric acid, as much cream of tartar as will saturate it.
This is best done by heating the water, agitating an excess of cream of
tartar in it, then allowing the water to cool, the excess of salt to
subside, and pouring off the clear solution. Now add to this solution,
while quite clear and bright, a little clear brandy, whisky, or other
spirit, and mix them by shaking. The solution will become ‘sick,’ like
the wine. Why is this?
It depends upon the fact that the bitartrate of potash, or cream of
tartar, is soluble to some extent in water, but almost insoluble
in alcohol. In a mixture of alcohol and water its solubility is
intermediate—the more alcohol the smaller the quantity that can be held
in solution (hydrochloric and most other acids, excepting tartaric,
increase its solubility in water). Thus, if we have a saturated
solution of this salt either in pure water or acidulated water, or
wine, the addition of alcohol throws some of it down in solid form, and
this makes the solution sick or turbid. When pure water or acidulated
water is used, as in the above-described experiment, crystals of the
salt are freely formed, and fall down readily; but with a complex
liquid like wine, containing saccharine and mucilaginous matter, the
precipitation takes place very slowly; the particles are excessively
minute, become entangled with the mucilage, &c., and thus remain
suspended for a long time, maintaining the turbidity accordingly.
Now, this bitartrate of potash is the characteristic natural salt
of the grape, and its unfermented juice is saturated with it. As
fermentation proceeds, and the sugar of the grape-juice is converted
into alcohol, the capacity of the juice for holding the salt in
solution diminishes, and it is gradually thrown down. But it does not
fall alone. It carries with it some of the colouring and extractive
matter of the grape-juice. This precipitate, in its crude state called
_argol_, or _roher Weinstein_, is the source from which we obtain the
tartaric acid of commerce, the cream of tartar, and other salts of
tartaric acid.
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