The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
Pure wine, containing its full supply of natural tartrate, will become
cloudy to a small extent, and gradually. A small precipitate will be
formed by the tartrate. The wine that contains either free sulphuric
acid or any of its compounds will yield _immediately_ a copious white
precipitate like chalk, but much more dense. This is sulphate of
baryta. The experiment may be made in a common wine-glass, but better
in a cylindrical test-tube, as, by using in this a fixed quantity in
each experiment, a rough notion of the relative quantity of sulphate
may be formed by the depth of the white layer after all has come down.
To determine this _accurately_, the wine, after applying the test,
should be filtered through proper filtering paper, and the precipitate
and paper burnt in a platinum or porcelain crucible and then weighed;
but this demands apparatus not always available, and some technical
skill. The simple demonstration of the copious precipitation is
instructive, and those of my readers who are practical chemists, but
have not yet applied this test to such wines, will be astonished, as I
was, at the amount of precipitation.
I may add that my first experience was upon a sample of dry sherry,
brought to me by a friend who bought his wine of a respectable
wine-merchant, and paid a high price for it, but found that it
disagreed with him; it contained an alarming quantity of free sulphuric
acid. Since that I have tested scores of samples, some of the finest in
the market, sent to me by a conscientious importer as the best he could
obtain, and these contained sulphate of potash instead of bitartrate.
My friend, the sherry-merchant, could not account for it, though he
was most anxious to do so. This was about three years ago. By dint of
inquiry and cross-examination of experts in the wine trade, I have,
I believe, discovered the origin of the sulphate of potash that is
contained in the samples that the British wine-merchant sells as he
buys, and conscientiously believes to be pure.
At first I hunted up all the information I could obtain from books
concerning the manufacture of sherry; learned that the grapes are
usually sprinkled with a little powdered sulphur as they are placed
in the vats prior to stamping. The quantity thus added, however, is
quite insufficient to account for the sulphur compounds in the samples
of wine I examined. Another source is described in the books—that
from sulphuring the casks. This process consists simply of burning
sulphur inside a partially-filled or empty cask, until the exhaustion
of free oxygen and its replacement by sulphurous acid renders further
combustion impossible. The cask is then filled with the wine. This
would add a little of sulphurous acid, but still not sufficient.
Public-domain text, read in full here on John Shaqi.
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