The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
The juices of lean meat may be extracted very completely without
cooking the meat at all, merely by mincing it and then placing it in
cold water. _Maceration_ is the proper name for this treatment. The
philosophy of this is interesting, and so little understood in the
kitchen that I must explain its rudiments.
If two liquids capable of mixing together, but of different densities,
be placed in the same vessel, the denser at the bottom, they will
mix together in defiance of gravitation, the heavy liquid rising and
spreading itself throughout the lighter, and the lighter descending and
diffusing itself through the heavier.
Thus, concentrated sulphuric acid (oil of vitriol) which has nearly
double the density of water, may be placed under water by pouring water
in a tall glass jar, and then carefully pouring the acid down a funnel
with a long tube, the bottom end of which touches the bottom of the
jar. At first the heavy liquid pushes up the lighter, and its upper
surface may be distinctly seen with that of the lighter resting upon
it. This is better shown if the water be coloured by a blue tincture
of litmus, which is reddened by the acid. A red stratum indicates the
boundaries of the two liquids. Gradually the reddening proceeds upwards
and downwards, the whole of the water changes from blue to red, and the
acid becomes tinged.
Graham worked for many years upon the determination of the laws of this
diffusion, and the rates at which different liquids diffused into each
other. His method was to fill small jars of uniform size and shape
(about 4 oz. capacity) with the saline or other dense solution, place
upon the ground mouth of the jar a plate-glass cover, then immerse it,
when filled, in a cylindrical glass vessel containing about 20 oz. of
distilled water. The cover being very carefully removed, diffusion was
allowed to proceed for a given time, and then by analysis the amount of
transfer into the distilled water was determined.
I must resist the temptation to expound the very interesting results
of these researches, merely stating that they prove this diffusion
to be no mere accidental mixing, but an action that proceeds with a
regularity reducible to simple mathematical laws. One curious fact
I may mention—viz. that on comparing the solutions of a number of
different salts, those which crystallise in the same forms have similar
rates of diffusion. The law that bears the most directly upon cookery
is that ‘the quantity of any substance diffused from a solution of
uniform strength increases as the temperature rises.’ The application
of this will be seen presently.
Public-domain text, read in full here on John Shaqi.
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