The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
Shellac is obtained from the resinous incrustation produced on the bark
of the twigs and branches of various tropical trees by the puncture of
the female "lac insect" (_Taccardia lacca_). The lac is removed from the
twigs by "beating" in water; the woody matter floats to the surface, and
the resin sinks to the bottom, and when removed forms what is known as
"seed-lac." Formerly, the solution, which contains the colouring matter
dissolved from the crude "stick-lac," was evaporated for recovery of the
so-called "lac-dye," but the latter is no longer used technically. The
seed-lac is bleached by boiling with sodium or potassium carbonate,
alum, or borax, and then, if it is not pale enough, is further bleached
by exposure to sunlight. It is now dried, melted, and mixed with a
certain proportion of rosin or of orpiment (a sulphide of arsenic)
according to the purpose for which it is desired. After further
operations of melting and straining, the lac is melted and spread into
thin sheets to form ordinary shellac, or is melted and dropped on to a
smooth surface to form "button-lac." Ordinary shellac almost invariably
contains some rosin, but good button-lac is free from this substance.
The presence of 5 per cent. of rosin in shellac can be detected by
dissolving in a little alcohol, pouring the solution into water, and
drying the fine impalpable powder which separates. This powder is
extracted with petroleum spirit, and the solution shaken with water
containing a trace of copper acetate. If rosin be present, the petroleum
spirit will be coloured emerald-green.
Borax, soda crystals, and ammonia are all used to dissolve shellac, and
it may be asked: Which of these is least injurious to wool? and why? How
is their action modified by the presence of dilute sulphuric acid in the
wool? I would say that soda crystals and ammonia are alkalis, and if
used strong, are sure to do a certain amount of injury to the fibre of
wool, and more if used hot than cold. Of the two, the ammonia will have
the least effect, especially if dilute, but borax is better than either.
The influence of a little sulphuric acid in the wool would be in the
direction of neutralising some of the ammonia or soda, and shellac, if
dissolved in the alkalis, would be to some extent precipitated on the
fibre, unless the alkali, soda or ammonia, were present in sufficient
excess to neutralise that sulphuric acid and to leave a sufficient
balance to keep the shellac in solution. Borax, which is a borate of
soda, would be so acted on by the sulphuric acid that some boric acid
would be set free, the sulphuric acid robbing some of that borax of its
soda. This boric acid would not be nearly so injurious to wool as
carbonate of soda or ammonia would.
Public-domain text, read in full here on John Shaqi.
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