The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
The best solvent for shellac, however, in the preparation of the
stiffening and proofing mixture for hats, is probably wood spirit or
methylated spirit. A solution of shellac in wood spirit is indeed used
for the spirit-proofing of silk hats, and to some extent of felt hats,
and on the whole the best work, I believe, is done with it. Moreover,
borax is not a cheap agent, and being non-volatile it is all left behind
in the proofed material, whereas wood spirit or methylated spirit is a
volatile liquid, _i.e._ a liquid easily driven off in vapour, and after
application to the felt it may be almost all recovered again for re-use.
In this way I conceive the use of wood spirit would be both more
effective and also cheaper than that of borax, besides being most
suitable in the case of any kind of dyes and colours to be subsequently
applied to the hats.
_Wood Spirit._--Wood spirit, the pure form of which is methyl alcohol,
is one of the products of the destructive distillation of wood. The wood
is distilled in large iron retorts connected to apparatus for condensing
the distillation products. The heating is conducted slowly at first, so
that the maximum yield of the valuable products--wood acid (acetic acid)
and wood spirit--which distil at a low temperature, is obtained. When
the condensed products are allowed to settle, they separate into two
distinct layers, the lower one consisting of a thick, very dark tar,
whilst the upper one, much larger in quantity, is the crude wood acid
(containing also the wood spirit), and is reddish-yellow or
reddish-brown in colour. This crude wood acid is distilled, and the wood
spirit which distils off first is collected separately from the acetic
acid which afterwards comes over. The acid is used for the preparation
of alumina and iron mordants (see next lecture), or is neutralised with
lime, forming grey acetate of lime, from which, subsequently, pure
acetic acid or acetone is prepared. The crude wood spirit is mixed with
milk of lime, and after standing for several hours is distilled in a
rectifying still. The distillate is diluted with water, run off from any
oily impurities which are separated, and re-distilled once or twice
after treatment with quicklime.
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