The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
COO·C_{20}H_{39}
/
becomes Phæophytin _b_, C_{32}H_{30}O_{2}N_{4}
\
COO·CH_{3}
Similarly,
Isochlorophyllin _a_, becomes Phytochlorin _e_,
Chlorophyllin _a_, becomes Phytochlorin _f_, and _g_,
COOH
/
C_{32}H_{32}ON_{4}
\
COOH
Isochlorophyllin _b_, becomes Phytorhodin _g_
Chlorophyllin _b_, becomes Phytorhodin _i_ and _k_,
COOH
/
C_{32}H_{30}O_{2}N_{4}
\
COOH
And bodies known as "porphyrins" are similarly derived from all the other
known phyllins.
For example: cyanophyllin, MgC_{31}H_{32}N_{4}(COOH)_{2}, becomes
cyanoporphyrin, C_{31}H_{34}N_{4}(COOH)_{2}; ætiophyllin,
MgC_{31}H_{34}N_{4}, becomes ætioporphyrin, C_{31}H_{36}N_{4}, etc.
Phytochlorin _e_ and phytorhodin _g_ are the chief products of the
decomposition by acids of the chlorophylls. Indeed, it was the production
of these compounds which led to the discovery of the existence of the two
chlorophylls. When treated with alkalies, they lose their carboxyl groups
and become ætioporphyrin.
=Decomposition of the Chlorophylls by Oxidation and Reduction.=--When acted
upon by oxidizing agents, such as chromic acid, the porphyrins yield two
chief oxidation products, which are pyrrole derivatives having the
following formulas,
CH_{3}-C-CO CH_{3}-C-CO
║ \ ║ \
║ NH ║ NH
║ / ║ /
CH_{3}-CH_{2}-C-CO HOOC-CH_{2}-CH_{2}-C-CO
Methylethylmalein imide Hæmatinic acid imide
By reduction, there have been obtained from the chlorophylls and the
various porphyrins, three isomeric pyrrole derivatives having the following
formulas,
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