The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
CHAPTER X
FATS AND OILS, WAXES, AND LIPOIDS
Included in this group are several different kinds of compounds which have
similar physical properties, and which, in general, belong to the type of
organic compounds known as esters, i.e., alcoholic salts of organic acids.
The terms "oil," "fat," and "wax," are generally applied more or less
indiscriminately to any substance which has a greasy feeling to the touch
and which does not mix with, but floats on, water. There are many oils
which are of mineral origin which are entirely different in composition
from natural fats. These have no relation to plant life and will not be
considered here.
The natural fats, vegetable oils, and plant waxes are all esters. There is
no essential difference between a fat and an oil, the latter term being
usually applied to a fat which is liquid at ordinary temperatures. The
waxes, however, are different in chemical composition from the fats and
oils, being esters of monohydric alcohols of high molecular weight, such as
cetyl alcohol, C_{16}H_{33}OH, myristic alcohol, C_{30}H_{61}OH, and
cholesterol, C_{27}H_{45}OH; whereas the fats and oils are all esters of
the trihydric alcohol glycerol, C_{3}H_{5}(OH)_{3}. Lipoids are much more
complex esters, having some nitrogenous, or phosphorus-containing, group
and sometimes a sugar in combination with the fatty acids and glycerol
which make up the characteristic part of their structure.
In general, waxes and lipoids have a harder consistency than fats: but this
is not always the case, since "wool-fat" and spermaceti, both of which are
true waxes in composition, are so nearly liquid in form as to be commonly
called fats; while certain true fats, like "Japan wax," are so hard as to
be commonly designated as waxes. It is plain that physical properties alone
cannot be relied upon in the classification of these bodies. In fact, there
is no single definite property by which members of this group can be
accurately identified. There are many other types of substances belonging
to entirely different chemical groups, which have oily, or fat-like,
properties.
A. FATS AND OILS
OCCURRENCE
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