The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
Fats can be artificially synthetized by heating mixtures of glycerol and
fatty acids, under considerable pressure, for some time at temperatures of
200° to 240° C.; or by heating a mixture of the disulfuric ester of glycerol
with a fatty acid dissolved in sulfuric acid. Recently, fatty acids have
been prepared from carbohydrates, by first breaking the hexoses down into
three-carbon compounds, then carefully oxidizing these to pyruvic acid,
CH_{3}·CO·COOH, which can then be condensed into acids having longer
chains. The violent reagents and long-continued processes which must be
employed for the artificial hydrolysis or synthesis of the fats are in
sharp contrast with the easy and rapid transition of carbohydrates to
fats, and _vice versa_, which take place in both plant and animal
nutrition.
THE EXTRACTION OF OILS FROM PLANT TISSUES
There are three types of methods which are employed for the extraction of
oil from oil-bearing seeds, etc., either as a commercial industry or for
the purposes of scientific study. These are (1) by pressure; (2) extraction
with volatile solvents; and (3) boiling the crushed seeds or fruits with
water.
By the first method, the seeds are first cleaned, then "decorticated"
(hulls removed), crushed or ground, then subjected to intense pressure in
an hydraulic press. In the commercial process, the ground seeds are first
pressed at ordinary temperature, which yields "cold-drawn" oil, then the
press cake is heated and pressed again, whereby "hot-drawn" oil is
obtained. The crude oil is refined by heating it to coagulate any albumin
which it may contain, and is sometimes bleached by different processes
before it is marketed. The press cake from many seeds, such as flaxseed
(linseed), cottonseed, etc., is ground up and sold for use as stock feed.
In the second method, the finely crushed seeds are treated with solvents
such as gasoline or carbon bisulfide, in an apparatus which is so arranged
that the fresh material is treated first with solvent which has already
passed through various successive lots of material and has become highly
charged with the oil, followed by other portions which contain less oil,
and finally by fresh solvent, whereby the last traces of oil are removed
from the material. The saturated solvent is transferred to suitable boilers
and the solvent distilled off and condensed for repeated use, leaving the
oil in the boiler in very pure form.
Extraction by boiling with water is sometimes used in the preparation of
castor oil and olive oil. In such cases, the crushed seeds are boiled with
water and the oil skimmed off as fast as it rises to the surface.
IDENTIFICATION OF FATS AND OILS
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