The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
The alkaloids are precipitated out of their solutions by various solutions
of chemical compounds, known as the "alkaloidal reagents": iodine dissolved
in potassium iodide solution gives a chocolate-brown precipitate; tannic
acid, phosphotungstic acid, phosphomolybdic acid, and mercuric iodide
solutions give colorless, amorphous precipitates; while gold chloride and
platinic chloride solutions give crystalline precipitates, many of which
have sharp melting points and can be used for the identification of
individual alkaloids. There are a great many specific color reactions for
individual alkaloids, which are important to toxicologists and pharmacists,
but which it would not be desirable to consider in detail here.
The alkaloids are conveniently divided into groups, according to the
characteristic closed-ring arrangements which they contain. The several
closed-ring arrangements which are found in common alkaloids, and upon
which their grouping is based, may be illustrated by the following
formulas:
H H H
H{2}_C---CH_{2} | \ /
| | C C
| | // \ / \
H{2}_C CH_{2} HC CH H_{2}C CH_{2}
\ / | | | |
N HC CH H_{2}C CH_{2}
| \\ / \ /
H N N
|
Pyrrolidine, C_{4}H_{9}N Pyrridine, C_{5}H_{5}N H
Piperidine, C_{5}H_{11}N
H H
\ / H
C |
/ \ H_{2}C-----C-----CH_{2}
H_{2}C CH_{2} | | |
| | | NH CH_{2}
HC CH | | |
|\ /| or H_{2}C-----C-----CH_{2}
| N | |
| /|\ | H
|/ H \|
H_{2}C-----CH_{2}
Tropane, C_{7}H_{13}N
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