The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
The sign of the electric charge on the particles of a sol may be either
negative or positive, depending upon the chemical nature and dielectric
constants of the two phases of the system. The proportion of the total
electric charge of the system which is of the opposite sign to that borne
by the dispersed particles is, of course, borne by the liquid which
constitutes the other phase. The origin of this electric charge on the
colloidal particles is, as yet, not known with certainty; but it seems
probable that it is due to a partial ionization of these small particles,
similar to, but not so complete as, that which takes place when compounds
which are soluble go into true solution in water, or other solvents which
bring about the dissociation of dissolved substances.
The conditions necessary to bring a solid substance into a colloidal
mixture with some liquid, or, in other words, to produce a suspensoid sol,
require that the proportion of liquid to solid shall be large and some
means of disintegrating the material which is to be dispersed into very
fine particles. Many common chemical reactions, if carried out in very
dilute solutions, result in the production of sols, especially if a small
amount of some emulsoid is present in the reacting mixture; sols produced
in this way are very stable, and the emulsoid which is used in stabilizing
the sol is known as a "protective colloid." Direct methods of
disintegration; such as reduction by chemical agents, discharge of a strong
electrical current through the substance which is to be dispersed while it
is submerged in the liquid, alternate treatment of finely ground material
with alkali and acid so as to frequently change the electric charge, etc.,
are utilized for bringing inorganic compounds into the colloidal state.
Suspensoids usually contain less than 1 per cent of the solid dispersed
through the liquid. In fact, extreme dilution is one of the necessary
conditions for suspensoid-formation.
Emulsoids are much more easily produced than are suspensoids. The property
of forming an emulsoid seems to be much more definitely a characteristic of
the substance in question than does the formation of sols from solids
which, under other conditions, may form true solutions. This difference may
be due to the fact that the liquids which easily form emulsoids (usually
those of organic origin) have very large molecules, so that the transfer
from molecular to colloidal condition involves much less change in such
cases than it does in the case of solid (inorganic) substances of
relatively low molecular weight. This view of the matter is further borne
out by the fact that solids which have very large molecules (generally of
organic origin) take on the colloidal form much more readily than do those
of small molecular size.
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