The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
Certain characteristics of adsorption phenomena are of interest and
importance from both the physiological and the industrial point of view.
The following may be mentioned: (_a_) _Amount of adsorption._ Relatively
more material is adsorbed out of dilute solutions than out of more
concentrated ones. An increase of ten times in the concentration of the
dissolved material results in only four times as much adsorption by the
colloidal substance which may be introduced into the two solutions. In
this, adsorption differs from chemical action, as the latter is
proportional to the concentration of the reacting material which is present
in the solution. (_b_) _Adsorption out of different liquids_, by the same
adsorbing body, is different in amount. It is usually greatest out of
water. Hence, many dyes may be adsorbed out of water by charcoal, porous
clay, etc., and if the latter be then introduced into alcohol, or ether,
the dye goes back into solution in these latter liquids. This process is
often used industrially and in the laboratory for the purification of such
substances when they are present in impure form in aqueous solutions. (_c_)
_Selective adsorption._ Different substances are not adsorbed out of the
same solvent to the same extent by the same adsorbing agent. Advantage is
taken of this fact when filter paper is used in the so-called "capillary
analysis" to separate different dyes, or other colloidal materials which
have been stained different colors, into alternate layer by reason of the
different rate at which the paper adsorbs the different materials out of
the solution in which they are present together. (_d_) _Similar relative
adsorption by different adsorbing agents._ Although different adsorbing
agents may possess varying active surfaces and hence, variable adsorbing
power, or rates of adsorption, they adsorb the same relative amounts of
different materials; i.e., if substance _A_ adsorbs more of _X_ than it
does of _Z_ out of any given solution, substance _B_ will likewise adsorb
more of _X_ than of _Z_ out of the same solution; although the actual
amounts adsorbed by _A_ may be quite different from those adsorbed by _B_.
CATALYSIS AFFECTED BY THE COLLOIDAL CONDITION
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