The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
Since hexoses have both alcoholic and aldehyde groups, and since either of
these types of groups may function in the linkage of the two hexoses to
form a disaccharide, it is possible for two hexoses, both of which are
reducing sugars to be linked together in three different ways: (1) through
an alcoholic group of each hexose, (2) through an alcoholic group of one
and the aldehyde group of the other, and (3) through the aldehyde group of
each hexose. Disaccharides linked in either of the first two ways will be
reducing sugars, since they still contain a potentially active aldehyde
group; but those of the third type will not be reducing sugars, since the
linkage through the aldehyde groups destroys their power of acting as
reducing agents. Examples of each of these three types of linkage are found
among the common disaccharides, as will be pointed out below.
The following table shows the general characteristics of the common
disaccharides.
_Type 1.--Aldehyde group potentially active, reducing sugars:_
Sugar Components
Maltose Glucose and glucose
Gentiobiose Glucose and glucose
Lactose Glucose and galactose
Melibiose Glucose and galactose
Turanose Glucose and fructose
_Type 2.--Non-reducing sugars:_
Sucrose Glucose and fructose
Trehalose Glucose and glucose
The disaccharides of Type 1 reduce Fehling's solution and form hydrazones
and osazones, although somewhat less readily than do the hexoses. They all
show mutarotation and exist in two modifications, indicating that the
component groups have the closed-ring arrangement.
The disaccharides of Type 2, since they contain no potentially active
aldehyde group, do not reduce Fehling's solution, nor form osazones;
neither do they exhibit mutarotation. The only disaccharides which occur as
such in plants are of this type. Disaccharides of Type 1 may be obtained by
the hydrolysis of other, more complex, carbohydrates.
All disaccharides are easily hydrolyzed into mixtures of their component
hexoses, by boiling with dilute mineral acids, or by treatment with certain
specific enzymes which are adapted to the particular disaccharide in each
case (see page 55, also Chapter XIV).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account