The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
=Isomaltose= is a synthetic sugar, obtained by Fischer, by condensing
two molecules of glucose. Its properties are quite similar to those of
maltose, but it yields a slightly different osazone and is not fermentable
by yeast. These differences are explained by the assumption that this
sugar is a glucose-[beta]-glucoside, while normal maltose is a
glucose-[alpha]-glucoside.
=Gentiobiose= is a disaccharide which results from the partial hydrolysis
of the trisaccharide _gentianose_ (see page 53). It is very similar in its
general properties to isomaltose. =Cellobiose= is a disaccharide which
results from the hydrolysis of cellulose. It is a reducing sugar, forms an
osazone, and resembles maltose.
Maltose, isomaltose, gentiobiose, and cellobiose, are all
glucose-glucosides, the difference between them being undoubtedly due to
linkage being between different alcoholic groups in the glucose molecules.
The disaccharide =lactose= is a glucose-galactoside. It is the sugar which
is present in the milk of all mammals. It has never been found in plants.
=Melibiose=, which is the corresponding vegetable glucose-galactoside, may
be obtained by the partial hydrolysis of the trisaccharide _raffinose_ (see
below). It is a reducing sugar; forms a characteristic osazone; and
exhibits mutarotation. It is not fermented by ordinary top-yeasts, but is
first hydrolyzed and then fermented by the enzymes present in
bottom-yeasts.
TRISACCHARIDES
Trisaccharides, as the name indicates, consist of three hexoses (or
monosaccharides) linked together by the dropping out of two molecules of
water. Their formula is C_{18}H_{32}O_{16}. When completely hydrolyzed,
they yield three molecules of monosaccharides; when partially hydrolyzed,
one each of a disaccharide and a monosaccharide.
One trisaccharide of the reducing sugar type, namely _rhamnose_, exists in
plants as a constituent of the glucoside xanthorhamnin. It is composed of
one molecule of glucose united to two molecules of rhamnose (methyl
pentose, C_{6}H_{12}O_{5}). It is of interest only in connection with the
properties of the glucoside in which it is present (see page 84).
Three trisaccharides which are non-reducing sugars are found in plants;
namely, raffinose, gentianose, and melizitose.
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