The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
Cellulose is acted upon by caustic alkalies in a variety of ways. When
fused with a mixture of dry sodium and potassium hydroxides, it is
decomposed into oxalic and acetic acids. When heated with a 10 to 15 per
cent solution of caustic soda, cellulose fibers thicken and become
translucent, thus resembling silk fibers. This process, known as
"Mercerizing," is largely used for the production of commercial fabrics.
Acids also act on cellulose in a variety of ways. When heated with nitric
acid (sp. gr. 1.25), it is converted into _oxycellulose_; while dilute
sulfuric acid, under similar conditions, yields _hydro-cellulose_, a
substance having the formula C_{12}H_{22}O_{11}, which retains the fibrous
structure of the original cellulose but which, when dry, may be rubbed up
into a fine powder. Concentrated nitric acid, or better, a mixture of
concentrated nitric and sulfuric acids, acts upon cellulose, converting it
into various nitro-derivatives, several of which have great industrial
value. The number of NO_{3} groups which unite with the cellulose molecule
under these conditions depends upon the temperature, pressure, etc.,
employed during the nitration process; di-, tri-, tetra-, penta-, and
hexanitrates are all known. _Pyroxylin_, or _collodion_, is a mixture
of the tetra- and penta-nitrates, which is soluble in alcohol and is
used in surgery, in photography, and in the manufacture of celluloid,
which is a mixture of collodion and camphor. The hexanitrate,
C_{12}H_{14}(NO_{3})_{6}O_{4}, is the violent explosive known as
_gun-cotton_.
Gentler oxidizing agents, such as "bleaching powder," etc., have no effect
upon cellulose, and hence are extensively used in the treatment of cotton
and other vegetable fibers, in preparation for their use in the manufacture
of textiles, paper, etc.
Cellulose is indigestible in the alimentary tract of animals, but the
putrefactive bacteria which are generally present there ferment it, with
the production of acids of the "fatty acid" series, carbon dioxide,
methane, and hydrogen. Excessive fermentations of this kind are responsible
for the distressing phenomenon known as "bloat."
The =compound celluloses= comprise the larger proportion of the material of
the woody stems of plants. They consist of a base of true cellulose, which
is either encrusted with or chemically combined with some non-cellulose
constituent. Depending upon the nature of the non-cellulose component, the
compound celluloses are divided into three main groups, known respectively
as (1) ligno-celluloses, (2) pecto-celluloses, and (3) adipo-, or
cuto-celluloses. As the names indicate, the non-cellulose component in the
first group is lignin; in the second, pectic substances; and in the third,
fats or waxes.
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