The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
O O
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4 4 ║ 4'
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Flavone Anthocyan
1 1
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The red dyes which were formerly obtained from madder, the powdered roots
of _Rubia tinctoria_, but are now almost wholly artificially synthetized,
consist of at least four different glucosides, the organic group of which,
in each case, is an hydroxy-derivative of anthraquinone. The most important
of these is _ruberythric acid_, composed of two molecules of glucose linked
with one of alizarin (1,2, dioxyanthraquinone). _Xanthopurpurin_ contains
1,3, dioxyanthraquinone, which is isomeric with alizarin; and _rubiadin_ is
a monomethyl (the CH_{3} being in the 4 position), derivative of this
compound. _Purpurin_ is a glucoside of 1,2,4, trioxyanthraquinone.
The soluble yellow pigments are generally glucosides of hydroxy-derivatives
of xanthone or flavone, known as oxyxanthones or oxyflavones. The sugars
which are united to these nuclei vary greatly, so that there are a great
variety of yellow, white, or colorless flavone or xanthone pigment
compounds. These compounds are almost universally present in plants. For
example, one typical set of examinations of the wood, bark, leaves, and
flowers of over 240 different species of tropical plants showed that
flavone derivatives were present in every sample which was tested, the
pigments being usually located in the powdery coating of the epidermis of
the tissues.
The following typical examples will serve to illustrate the composition and
properties of the glucosides of this type.
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