Before leaving this subject we must call upon our readers to realize
what takes place in all heat engines. It is not merely that heat
produces mechanical effect, but that _a given quantity of heat
absolutely passes out of existence as heat in producing its equivalent
of work_. If, therefore, we could measure the mere heat produced in an
engine by the burning of a ton of coals, we should find it to be less
when the engine was doing work than when it was at rest.
In like manner, when a gas expands suddenly its temperature falls,
because a certain amount of its heat passes out of existence in the act
of producing mechanical effect.
157. We have thus endeavoured to show under what conditions absorbed
heat may be converted into mechanical effect. This absorbed heat
embraces (Art. 110) two varieties of energy, one of these being
molecular motion, and the other molecular energy of position.
Let us now, therefore, endeavour to ascertain under what circumstances
the one of these varieties may be changed into the other. It is well
known that it takes a good deal of heat to convert a kilogramme of ice
into water, and that when the ice is melted the temperature of the
water is not perceptibly higher than that of the ice. It is equally
well known that it takes a great deal of heat to convert a kilogramme
of boiling water into steam, and that when the transformation is
accomplished, the steam produced is not perceptibly hotter than the
boiling water. In such cases the heat is said to become latent.
Now, in both these cases, but more obviously in the last, we may
suppose that the heat has not had its usual office to perform, but
that, instead of increasing the motion of the molecules of water, it
has spent its energy in tearing them asunder from each other, against
the force of cohesion which binds them together.
Indeed, we know as a matter of fact that the force of cohesion which is
perceptible in boiling water is apparently absent from steam, or the
vapour of water, because its molecules are too remote from one another
to allow of this force being appreciable. We may, therefore, suppose
that a large part, at least, of the heat necessary to convert boiling
water into steam is spent in doing work against molecular forces.
When the steam is once more condensed into hot water, the heat thus
spent reassumes the form of molecular motion, and the consequence
is that we require to take away somehow all the latent heat of a
kilogramme of steam before we can convert it into boiling water. In
fact, if it is difficult and tedious to convert water into steam, it is
difficult and tedious to convert steam into water.
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