A solid, for instance, may be changed into a liquid, or a gas into
a liquid. Sometimes the one change counteracts the other as far as
apparent heat is concerned; but sometimes, too, they co-operate
together to increase the result. Thus, when a gas is absorbed by water,
much heat is evolved, and we may suppose the result to be due in part
to chemical combination, and in part to the condensation of the gas
into a liquid, by which means its latent heat is rendered sensible. On
the other hand, when a liquid unites with a solid, or when two solids
unite with one another, and the product is a liquid, we have very often
the absorption of heat, the heat rendered latent by the dissolution
of the solid being more than that generated by combination. Freezing
mixtures owe their cooling properties to this cause; thus, if snow and
salt be mixed together, they liquefy each other, and the result is
brine of a temperature much lower than that of either the ingredients.
168. When heterogeneous metals, such as zinc and copper, are soldered
together, we have apparently a conversion of the energy of chemical
separation into that of _electrical separation_. This was first
suggested by Volta as the origin of the electrical separation which
we see in the voltaic current, and recently its existence has been
distinctly proved by Sir W. Thomson.
To render manifest this conversion of energy, let us solder a piece of
zinc and copper together--if we now test the bar by means of a delicate
electrometer we shall find that the zinc is positively, while the
copper is negatively, electrified. We have here, therefore, an instance
of the transmutation of one form of energy of position into another; so
much energy of chemical separation disappearing in order to produce so
much electrical separation. This explains the fact recorded in Art. 93,
where we saw that if a battery be insulated and its poles kept apart,
the one will be charged with positive, and the other with negative,
electricity.
169. But further, when such a voltaic battery is in action, we have a
transmutation of chemical separation into _electricity in motion_. To
see this, let us consider what takes place in such a battery.
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